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- W2324251202 abstract "This report describes the reactivities of POCOP-type pincer complexes of nickel bearing a trimethylsiloxide ligand. The complex {κP,κC,κP-2,6-(i-Pr2PO)2C6H3}Ni(OSiMe3) (1-OSiMe3) reacts with 2,4,6-Me3-C6H2OH (MesOH) to give the stable derivative 1-OMes, whereas the corresponding tert-butoxide derivative could not be prepared. Reaction of 1-OSiMe3 and its aliphatic analogue {κP,κC,κP-(i-Pr2POCH2)2CH}Ni(OSiMe3) (2-OSiMe3) with Ph3SiOH led to facile formation of the corresponding protonolysis products 1-OSiPh3 and 2-OSiPh3. Treating 1-OSiMe3 or 2-OSiMe3 with Me3SiN3 gave the azide derivatives 1-N3 or 2-N3 in high isolated yields, whereas the analogous reactions with Me3SiCF3 gave 2-CF3 but not 1-CF3. These observations allow us to compare the reactivities of the Ni–OSiMe3 moiety as a function of pincer ligand backbone. All new complexes have been characterized fully. The reaction of the azide derivatives with benzyl bromide led to the formation of benzyl azide and the corresponding bromo derivatives; 2-N3 pr..." @default.
- W2324251202 created "2016-06-24" @default.
- W2324251202 creator A5041877922 @default.
- W2324251202 creator A5048611374 @default.
- W2324251202 creator A5076355027 @default.
- W2324251202 date "2014-11-11" @default.
- W2324251202 modified "2023-10-02" @default.
- W2324251202 title "POCOP-Ligated Nickel Siloxide Complexes: Syntheses, Characterization, and Reactivities" @default.
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- W2324251202 doi "https://doi.org/10.1021/om500916d" @default.
- W2324251202 hasPublicationYear "2014" @default.
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