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- W2324358992 abstract "The reaction of phenyl(2,4,6-trimethylphenyl)phosphine with a substituted benzoquinone in the presence of a chiral phosphapalladacycle complex as a catalyst and triethylamine in chloroform at −45 °C proceeded in a new type of addition manner to give a high yield of a 4-hydroxyphenyl phenyl(2,4,6-trimethylphenyl)phosphinite with 98% enantioselectivity, which is a versatile intermediate readily convertible into various phosphines and their derivatives with high enantiomeric purity." @default.
- W2324358992 created "2016-06-24" @default.
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- W2324358992 date "2014-03-20" @default.
- W2324358992 modified "2023-10-01" @default.
- W2324358992 title "Asymmetric Synthesis of <i>P</i>-Stereogenic Diarylphosphinites by Palladium-Catalyzed Enantioselective Addition of Diarylphosphines to Benzoquinones" @default.
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- W2324358992 doi "https://doi.org/10.1021/ja501007t" @default.
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