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- W2324388210 abstract "Six new polyketide derivatives, including pestalpolyol I (1), pestapyrones A (2) and B (3), (R)-periplanetin D (6), pestaxanthone (7), norpestaphthalide A (8), and an isolation artifact pestapyrone C (4), were obtained from extracts of the endophytic fungus Pestalotiopsis clavispora isolated from the Mangrove plant Rhizophora harrisonii. In addition, seven known metabolites, including similanpyrone B (5), (R,S)-5,7-dihydroxy-3-(1-hydroxyethyl)phthalide (9), for which we propose the trivial name norpestaphthalide B, pestaphthalides A (10) and B (11), 2-epi-herbarumin II (12), and pestalotiollides A (13) and B (14) were isolated. The structures of the new compounds were unambiguously elucidated on the basis of one- and two-dimensional NMR spectroscopy, as well as by high-resolution mass spectrometry. All compounds were tested for their cytotoxicity against the mouse lymphoma cell line L5178Y. Compound 1 exhibited strong activity with an IC50 value of 4.10 μM. All other compounds (2–14) proved to be inactive (IC50 >10 μM) in this assay." @default.
- W2324388210 created "2016-06-24" @default.
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- W2324388210 date "2016-05-01" @default.
- W2324388210 modified "2023-10-05" @default.
- W2324388210 title "Polyketides from the Mangrove-derived fungal endophyte Pestalotiopsis clavispora" @default.
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- W2324388210 doi "https://doi.org/10.1016/j.tetlet.2016.03.101" @default.
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