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- W2324389718 abstract "The equilibrium constants for the liquid-phase dehydration of 1-octanol to 1-(octyloxy)octane (DNOE) and water have been determined in the temperature range (413 to 453) K over Amberlyst 70. The equilibrium constants for the main side reactions, intramolecular dehydration of 1-octanol to 1-octene and 1-octene isomerization to 2-octene, have been determined as well. Etherification of 1-octanol was shown to be exothermic, with reaction enthalpy change of (−13.6 ± 1.7) kJ·mol–1 at 298.15 K. The standard formation enthalpy of 1-(octyloxy)octane was computed to be (−581 ± 2) kJ·mol–1, in good agreement with the estimated value by a modified Benson method. A standard molar entropy of (658 ± 4) J·mol–1·K–1 in the liquid phase has been found for 1-(octyloxy)octane from the entropy change of reaction at 298.15 K. Intramolecular dehydration of 1-octanol has been found to be endothermic and isomerization of 1-octene to 2-octene exothermic." @default.
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- W2324389718 date "2013-02-28" @default.
- W2324389718 modified "2023-09-27" @default.
- W2324389718 title "Chemical Equilibrium of the Liquid-Phase Dehydration of 1-Octanol to 1-(Octyloxy)octane" @default.
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- W2324389718 doi "https://doi.org/10.1021/je301236k" @default.
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