Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324431471> ?p ?o ?g. }
- W2324431471 endingPage "684" @default.
- W2324431471 startingPage "678" @default.
- W2324431471 abstract "Hydrosilylation catalyzed by a high-valent nitridoruthenium(VI) compound, [RuN(saldach)(CH3OH)]+[ClO4]− (1, where saldach is the dianion of racemic N,N′-cyclohexan-diyl-bis(salicylideneimine)) is described. Using phenylsilane as reductant, a variety of unsaturated organic substrates, including aldehydes, ketones, and imines, are effectively reduced to alcohols and amines, respectively, accompanied by the redistribution of PhSiH3 at silicon. Mechanistic studies indicate that the catalysis proceeds via silane activation rather than carbonyl activation, and the silane is likely activated via multiple pathways, including a radical-based pathway." @default.
- W2324431471 created "2016-06-24" @default.
- W2324431471 creator A5043051746 @default.
- W2324431471 creator A5063376192 @default.
- W2324431471 creator A5079071180 @default.
- W2324431471 creator A5091452182 @default.
- W2324431471 date "2013-03-12" @default.
- W2324431471 modified "2023-09-27" @default.
- W2324431471 title "Scope and Mechanistic Studies of Catalytic Hydrosilylation with a High-Valent Nitridoruthenium(VI)" @default.
- W2324431471 cites W1967628397 @default.
- W2324431471 cites W1970505634 @default.
- W2324431471 cites W1976597396 @default.
- W2324431471 cites W1977676315 @default.
- W2324431471 cites W1992775007 @default.
- W2324431471 cites W1994750002 @default.
- W2324431471 cites W1996455423 @default.
- W2324431471 cites W1997697733 @default.
- W2324431471 cites W1998842511 @default.
- W2324431471 cites W1999970965 @default.
- W2324431471 cites W2003639645 @default.
- W2324431471 cites W2004203072 @default.
- W2324431471 cites W2004453684 @default.
- W2324431471 cites W2013502629 @default.
- W2324431471 cites W2015036859 @default.
- W2324431471 cites W2017408363 @default.
- W2324431471 cites W2021936154 @default.
- W2324431471 cites W2023875511 @default.
- W2324431471 cites W2023933936 @default.
- W2324431471 cites W2031144663 @default.
- W2324431471 cites W2031662464 @default.
- W2324431471 cites W2035098018 @default.
- W2324431471 cites W2041158998 @default.
- W2324431471 cites W2041885115 @default.
- W2324431471 cites W2041912960 @default.
- W2324431471 cites W2047886810 @default.
- W2324431471 cites W2051784722 @default.
- W2324431471 cites W2054372444 @default.
- W2324431471 cites W2055116512 @default.
- W2324431471 cites W2058282121 @default.
- W2324431471 cites W2059369332 @default.
- W2324431471 cites W2059660367 @default.
- W2324431471 cites W2067006720 @default.
- W2324431471 cites W2067541626 @default.
- W2324431471 cites W2076087133 @default.
- W2324431471 cites W2081300517 @default.
- W2324431471 cites W2084889861 @default.
- W2324431471 cites W2090476367 @default.
- W2324431471 cites W2092218137 @default.
- W2324431471 cites W2092468909 @default.
- W2324431471 cites W2093575737 @default.
- W2324431471 cites W2093909158 @default.
- W2324431471 cites W2100944981 @default.
- W2324431471 cites W2104831549 @default.
- W2324431471 cites W2129758402 @default.
- W2324431471 cites W2145429661 @default.
- W2324431471 cites W2148553974 @default.
- W2324431471 cites W2149827743 @default.
- W2324431471 cites W2168132195 @default.
- W2324431471 cites W2172226014 @default.
- W2324431471 cites W2317320799 @default.
- W2324431471 cites W2317968933 @default.
- W2324431471 cites W2321353110 @default.
- W2324431471 cites W2324686881 @default.
- W2324431471 cites W2326897791 @default.
- W2324431471 cites W2330139649 @default.
- W2324431471 cites W2331251351 @default.
- W2324431471 cites W2949342357 @default.
- W2324431471 cites W2949614221 @default.
- W2324431471 cites W2949644621 @default.
- W2324431471 cites W2949745197 @default.
- W2324431471 cites W2953348298 @default.
- W2324431471 cites W3005379737 @default.
- W2324431471 doi "https://doi.org/10.1021/cs300848h" @default.
- W2324431471 hasPublicationYear "2013" @default.
- W2324431471 type Work @default.
- W2324431471 sameAs 2324431471 @default.
- W2324431471 citedByCount "44" @default.
- W2324431471 countsByYear W23244314712013 @default.
- W2324431471 countsByYear W23244314712014 @default.
- W2324431471 countsByYear W23244314712015 @default.
- W2324431471 countsByYear W23244314712016 @default.
- W2324431471 countsByYear W23244314712017 @default.
- W2324431471 countsByYear W23244314712018 @default.
- W2324431471 countsByYear W23244314712019 @default.
- W2324431471 countsByYear W23244314712020 @default.
- W2324431471 countsByYear W23244314712021 @default.
- W2324431471 countsByYear W23244314712022 @default.
- W2324431471 crossrefType "journal-article" @default.
- W2324431471 hasAuthorship W2324431471A5043051746 @default.
- W2324431471 hasAuthorship W2324431471A5063376192 @default.
- W2324431471 hasAuthorship W2324431471A5079071180 @default.
- W2324431471 hasAuthorship W2324431471A5091452182 @default.
- W2324431471 hasConcept C139066938 @default.
- W2324431471 hasConcept C161790260 @default.
- W2324431471 hasConcept C17744445 @default.
- W2324431471 hasConcept C178790620 @default.
- W2324431471 hasConcept C185592680 @default.
- W2324431471 hasConcept C199539241 @default.