Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324454089> ?p ?o ?g. }
- W2324454089 endingPage "12427" @default.
- W2324454089 startingPage "12420" @default.
- W2324454089 abstract "The behavior of pyrrole under high pressure has been investigated by in situ high-pressure synchrotron X-ray diffraction (XRD) and Raman scattering up to 34 GPa. A solid-to-solid transition at about 6.2 GPa with a large collapse of volume (∼40%) from Pnma to P21/c has been found after a liquid-to-solid transition at 0.6 GPa, which is caused by the molecular rotational repacking of π-stacking. This new phase P21/c plays a central role in the following pressure-induced polymerization due to the formation of a closed dimer, a very important precursor. The threshold of C···C distance with steric hindrance in dimer is about 1.62 Å at ∼10.2 GPa. After this steric hindrance is overcome, a crystal–amorphous transformation starts at ∼14.3 GPa. When completely released from 34 GPa, the recovered solid product with single bond is identified by in situ Raman measurement." @default.
- W2324454089 created "2016-06-24" @default.
- W2324454089 creator A5012486505 @default.
- W2324454089 creator A5020498964 @default.
- W2324454089 creator A5021878761 @default.
- W2324454089 creator A5025104574 @default.
- W2324454089 creator A5032950421 @default.
- W2324454089 creator A5036940201 @default.
- W2324454089 creator A5042523906 @default.
- W2324454089 creator A5051123510 @default.
- W2324454089 creator A5060409988 @default.
- W2324454089 creator A5068065542 @default.
- W2324454089 creator A5078331262 @default.
- W2324454089 creator A5080027890 @default.
- W2324454089 creator A5080381188 @default.
- W2324454089 date "2014-06-03" @default.
- W2324454089 modified "2023-10-06" @default.
- W2324454089 title "Pressure-Induced Diversity of π-Stacking Motifs and Amorphous Polymerization in Pyrrole" @default.
- W2324454089 cites W1964534634 @default.
- W2324454089 cites W1965774978 @default.
- W2324454089 cites W1969760208 @default.
- W2324454089 cites W1971441016 @default.
- W2324454089 cites W1975247060 @default.
- W2324454089 cites W1977069019 @default.
- W2324454089 cites W1983874564 @default.
- W2324454089 cites W1985175072 @default.
- W2324454089 cites W1992271299 @default.
- W2324454089 cites W1993993573 @default.
- W2324454089 cites W1997126459 @default.
- W2324454089 cites W2005457300 @default.
- W2324454089 cites W2007758037 @default.
- W2324454089 cites W2015889298 @default.
- W2324454089 cites W2024793068 @default.
- W2324454089 cites W2026836576 @default.
- W2324454089 cites W2028976916 @default.
- W2324454089 cites W2030187866 @default.
- W2324454089 cites W2030526855 @default.
- W2324454089 cites W2032667729 @default.
- W2324454089 cites W2032745331 @default.
- W2324454089 cites W2042199517 @default.
- W2324454089 cites W2043577929 @default.
- W2324454089 cites W2056964249 @default.
- W2324454089 cites W2078456583 @default.
- W2324454089 cites W2078807014 @default.
- W2324454089 cites W2079185228 @default.
- W2324454089 cites W2084972630 @default.
- W2324454089 cites W2088152768 @default.
- W2324454089 cites W2093163715 @default.
- W2324454089 cites W2104919283 @default.
- W2324454089 cites W2159752439 @default.
- W2324454089 cites W2327313040 @default.
- W2324454089 cites W2327385768 @default.
- W2324454089 cites W2330110239 @default.
- W2324454089 doi "https://doi.org/10.1021/jp412065p" @default.
- W2324454089 hasPublicationYear "2014" @default.
- W2324454089 type Work @default.
- W2324454089 sameAs 2324454089 @default.
- W2324454089 citedByCount "12" @default.
- W2324454089 countsByYear W23244540892014 @default.
- W2324454089 countsByYear W23244540892015 @default.
- W2324454089 countsByYear W23244540892016 @default.
- W2324454089 countsByYear W23244540892017 @default.
- W2324454089 countsByYear W23244540892018 @default.
- W2324454089 countsByYear W23244540892020 @default.
- W2324454089 countsByYear W23244540892021 @default.
- W2324454089 crossrefType "journal-article" @default.
- W2324454089 hasAuthorship W2324454089A5012486505 @default.
- W2324454089 hasAuthorship W2324454089A5020498964 @default.
- W2324454089 hasAuthorship W2324454089A5021878761 @default.
- W2324454089 hasAuthorship W2324454089A5025104574 @default.
- W2324454089 hasAuthorship W2324454089A5032950421 @default.
- W2324454089 hasAuthorship W2324454089A5036940201 @default.
- W2324454089 hasAuthorship W2324454089A5042523906 @default.
- W2324454089 hasAuthorship W2324454089A5051123510 @default.
- W2324454089 hasAuthorship W2324454089A5060409988 @default.
- W2324454089 hasAuthorship W2324454089A5068065542 @default.
- W2324454089 hasAuthorship W2324454089A5078331262 @default.
- W2324454089 hasAuthorship W2324454089A5080027890 @default.
- W2324454089 hasAuthorship W2324454089A5080381188 @default.
- W2324454089 hasConcept C120665830 @default.
- W2324454089 hasConcept C121332964 @default.
- W2324454089 hasConcept C149288129 @default.
- W2324454089 hasConcept C159985019 @default.
- W2324454089 hasConcept C169573571 @default.
- W2324454089 hasConcept C178790620 @default.
- W2324454089 hasConcept C185592680 @default.
- W2324454089 hasConcept C192562407 @default.
- W2324454089 hasConcept C201194858 @default.
- W2324454089 hasConcept C207114421 @default.
- W2324454089 hasConcept C21368211 @default.
- W2324454089 hasConcept C26873012 @default.
- W2324454089 hasConcept C2779546866 @default.
- W2324454089 hasConcept C33347731 @default.
- W2324454089 hasConcept C40003534 @default.
- W2324454089 hasConcept C44228677 @default.
- W2324454089 hasConcept C521977710 @default.
- W2324454089 hasConcept C56052488 @default.
- W2324454089 hasConcept C71240020 @default.