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- W2324492968 abstract "Degradable organic nanotubes were synthesized by a single-molecule templating of core–shell bottlebrush copolymers composed of an etchable inner block (polylactide) and a functional outer block (poly(styrene-co-maleic anhydride)). The pendant mercapto groups generated along the outer block chains by reacting the anhydride groups with cysteamine were oxidized to disulfide groups acting as degradable cross-linking units in the shell layer. Subsequent hydrolytic removal of the polyester inner core provided hollow organic nanotubes held together by disulfide groups as cross-linkers. The cleavage of disulfide linkers by reaction with dithiothreitol resulted in a complete disintegration of nanotube structures into small fragments." @default.
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- W2324492968 date "2012-06-29" @default.
- W2324492968 modified "2023-10-16" @default.
- W2324492968 title "Synthesis of Degradable Organic Nanotubes by Bottlebrush Molecular Templating" @default.
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- W2324492968 doi "https://doi.org/10.1021/mz3002287" @default.
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