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- W2324496952 abstract "The Cr VI oxidation of a mixture of dimethyl sulfoxide (DMSO) and oxalic acid (OXH 2 ) in aqueous acid media occurs much faster than that of either of the two substrates alone (DMSO reacts extremely slowly under the experimental conditions). In the mixture, both substrates undergo oxidation simultaneously in a ternary complex of Cr VI through a three electron transfer step (i.e. Cr VI → Cr III ), two electrons from DMSO and one electron from oxalic acid. Hitherto there has been a debate regarding the existence of a 3e transfer in a single step. The micellar effect may be considered as a probe for 3e transfer in a single step." @default.
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- W2324496952 date "2005-09-01" @default.
- W2324496952 modified "2023-09-23" @default.
- W2324496952 title "Micellar Effect on the Catalytic Co-Oxidation of Dimethyl Sulfoxide and Oxalic Acid by Chromium(VI) in Aqueous Acid Media: A Kinetic Study" @default.
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- W2324496952 doi "https://doi.org/10.3184/007967405779134047" @default.
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