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- W2324536473 endingPage "5989" @default.
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- W2324536473 abstract "Density functional theory (DFT) investigations revealed that 4-cyanopyridine was capable of homolytically cleaving the B-B σ bond of diborane via the cooperative coordination to the two boron atoms of the diborane to generate pyridine boryl radicals. Our experimental verification provides supportive evidence for this new B-B activation mode. With this novel activation strategy, we have experimentally realized the catalytic reduction of azo-compounds to hydrazine derivatives, deoxygenation of sulfoxides to sulfides, and reduction of quinones with B2 (pin)2 at mild conditions." @default.
- W2324536473 created "2016-06-24" @default.
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- W2324536473 date "2016-04-08" @default.
- W2324536473 modified "2023-10-16" @default.
- W2324536473 title "Homolytic Cleavage of a B−B Bond by the Cooperative Catalysis of Two Lewis Bases: Computational Design and Experimental Verification" @default.
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- W2324536473 doi "https://doi.org/10.1002/anie.201511917" @default.
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