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- W2324572160 abstract "The complexes [Ba[(C5Me5)2Ti2F7]2(hmpa)].(THF), 1.hmpa.(THF), and [Ba8Ti6F30I2(C5Me5)6(hmpa)6][I3]2.10(THF), 2[I3]2.10(THF), were prepared from [Hdmpy](+)[(C5Me5)2Ti2F7]- (dmpy = 2,6-dimethylpyridine), BaI2, and hmpa (hmpa = hexamethylphosphoramide). They were characterized by 1H and 19F NMR and IR spectroscopy and examined by single-crystal X-ray crystallography. The complexation equilibrium of the barium ion in 1 with hmpa and the dynamics of the barium ion moving on the fluorine surfaces of [(C5Me5)2Ti2F7]- in 1.hmpa have been studied by variable-temperature 19F NMR spectroscopy. The core of the complex 2[I3]2.10(THF) resembles the basic structural unit of the cubic perovskite." @default.
- W2324572160 created "2016-06-24" @default.
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- W2324572160 date "2004-02-01" @default.
- W2324572160 modified "2023-09-26" @default.
- W2324572160 title "Syntheses and Solid-State and Solution Structures of [Ba{(C5Me5)2Ti2F7}2(hmpa)] and [Ba8Ti6F30I2(C5Me5)6(hmpa)6][I3]2" @default.
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- W2324572160 doi "https://doi.org/10.1021/ic035256v" @default.
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