Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324629182> ?p ?o ?g. }
- W2324629182 endingPage "12867" @default.
- W2324629182 startingPage "12860" @default.
- W2324629182 abstract "Hydroxyl radical (•OH) is a highly reactive and unselective oxidant in atmospheric and aquatic systems. Current understanding limits the role of DOM-produced •OH as an oxidant in carbon cycling mainly to sunlit environments where •OH is produced photochemically, but a recent laboratory study proposed a sunlight-independent pathway in which •OH forms during oxidation of reduced aquatic dissolved organic matter (DOM) and iron. Here we demonstrate this non-photochemical pathway for •OH formation in natural aquatic environments. Across a gradient from dry upland to wet lowland habitats, •OH formation rates increase with increasing concentrations of DOM and reduced iron, with highest •OH formation predicted at oxic-anoxic boundaries in soil and surface waters. Comparison of measured vs expected electron release from reduced moieties suggests that both DOM and iron contribute to •OH formation. At landscape scales, abiotic DOM oxidation by this dark •OH pathway may be as important to carbon cycling as bacterial oxidation of DOM in arctic surface waters." @default.
- W2324629182 created "2016-06-24" @default.
- W2324629182 creator A5001802334 @default.
- W2324629182 creator A5010732510 @default.
- W2324629182 creator A5012594882 @default.
- W2324629182 creator A5022337602 @default.
- W2324629182 creator A5051228855 @default.
- W2324629182 creator A5058526751 @default.
- W2324629182 creator A5071436257 @default.
- W2324629182 date "2013-10-29" @default.
- W2324629182 modified "2023-10-14" @default.
- W2324629182 title "Dark Formation of Hydroxyl Radical in Arctic Soil and Surface Waters" @default.
- W2324629182 cites W1657977011 @default.
- W2324629182 cites W1681833908 @default.
- W2324629182 cites W1926950498 @default.
- W2324629182 cites W1964254681 @default.
- W2324629182 cites W1964668379 @default.
- W2324629182 cites W1971862621 @default.
- W2324629182 cites W1972105761 @default.
- W2324629182 cites W1975010088 @default.
- W2324629182 cites W1982842807 @default.
- W2324629182 cites W1983822766 @default.
- W2324629182 cites W2006426318 @default.
- W2324629182 cites W2010181898 @default.
- W2324629182 cites W2011129404 @default.
- W2324629182 cites W2012974465 @default.
- W2324629182 cites W2012991711 @default.
- W2324629182 cites W2013167592 @default.
- W2324629182 cites W2014465108 @default.
- W2324629182 cites W2014896747 @default.
- W2324629182 cites W2016182716 @default.
- W2324629182 cites W2017770982 @default.
- W2324629182 cites W2023575854 @default.
- W2324629182 cites W2025035189 @default.
- W2324629182 cites W2026470384 @default.
- W2324629182 cites W2029764853 @default.
- W2324629182 cites W2030348009 @default.
- W2324629182 cites W2033823231 @default.
- W2324629182 cites W2042796545 @default.
- W2324629182 cites W2046433748 @default.
- W2324629182 cites W2055159418 @default.
- W2324629182 cites W2059294660 @default.
- W2324629182 cites W2063042384 @default.
- W2324629182 cites W2066370210 @default.
- W2324629182 cites W2076986542 @default.
- W2324629182 cites W2078563229 @default.
- W2324629182 cites W2086117181 @default.
- W2324629182 cites W2091913250 @default.
- W2324629182 cites W2094677922 @default.
- W2324629182 cites W2096548139 @default.
- W2324629182 cites W2110534188 @default.
- W2324629182 cites W2142340503 @default.
- W2324629182 cites W2150364181 @default.
- W2324629182 cites W2151642452 @default.
- W2324629182 cites W2160914961 @default.
- W2324629182 cites W2313171181 @default.
- W2324629182 cites W2316689429 @default.
- W2324629182 cites W2334827312 @default.
- W2324629182 doi "https://doi.org/10.1021/es4033265" @default.
- W2324629182 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24111975" @default.
- W2324629182 hasPublicationYear "2013" @default.
- W2324629182 type Work @default.
- W2324629182 sameAs 2324629182 @default.
- W2324629182 citedByCount "181" @default.
- W2324629182 countsByYear W23246291822014 @default.
- W2324629182 countsByYear W23246291822015 @default.
- W2324629182 countsByYear W23246291822016 @default.
- W2324629182 countsByYear W23246291822017 @default.
- W2324629182 countsByYear W23246291822018 @default.
- W2324629182 countsByYear W23246291822019 @default.
- W2324629182 countsByYear W23246291822020 @default.
- W2324629182 countsByYear W23246291822021 @default.
- W2324629182 countsByYear W23246291822022 @default.
- W2324629182 countsByYear W23246291822023 @default.
- W2324629182 crossrefType "journal-article" @default.
- W2324629182 hasAuthorship W2324629182A5001802334 @default.
- W2324629182 hasAuthorship W2324629182A5010732510 @default.
- W2324629182 hasAuthorship W2324629182A5012594882 @default.
- W2324629182 hasAuthorship W2324629182A5022337602 @default.
- W2324629182 hasAuthorship W2324629182A5051228855 @default.
- W2324629182 hasAuthorship W2324629182A5058526751 @default.
- W2324629182 hasAuthorship W2324629182A5071436257 @default.
- W2324629182 hasConcept C104779481 @default.
- W2324629182 hasConcept C107872376 @default.
- W2324629182 hasConcept C108970007 @default.
- W2324629182 hasConcept C130309983 @default.
- W2324629182 hasConcept C132215390 @default.
- W2324629182 hasConcept C139066938 @default.
- W2324629182 hasConcept C140205800 @default.
- W2324629182 hasConcept C158787203 @default.
- W2324629182 hasConcept C159985019 @default.
- W2324629182 hasConcept C175327387 @default.
- W2324629182 hasConcept C178790620 @default.
- W2324629182 hasConcept C185592680 @default.
- W2324629182 hasConcept C18903297 @default.
- W2324629182 hasConcept C192562407 @default.
- W2324629182 hasConcept C2776778087 @default.
- W2324629182 hasConcept C36574619 @default.