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• W2324669492 endingPage "6210" @default.
• W2324669492 startingPage "6200" @default.
• W2324669492 abstract "Halogen bonding interactions between halide anions and neutral polyiodinated linkers are used for the elaboration of anion organic frameworks, by analogy with well-known MOF derivatives. The extended, 3-fold symmetry, 1,3,5-tris(iodoethynyl)-2,4,6-trifluorobenzene (1) cocrystallizes with a variety of halide salts, namely, Et3S(+)I(-), Et3MeN(+)I(-), Et4N(+)Br(-), Et3BuN(+)Br(-), Me-DABCO(+)I(-), Bu3S(+)I(-), Bu4N(+)Br(-), Ph3S(+)Br(-), Ph4P(+)Br(-), and PPN(+)Br(-). Salts with 1:1 stoichiometry formulated as (1)·(C(+),X(-)) show recurrent formation of corrugated (6,3) networks, with the large cavities thus generated, filled either by the cations and solvent (CHCl3) molecules and/or by interpenetration (up to 4-fold interpenetration). The 2:1 salt formulated as (1)2·(Et3BuN(+)Br(-)) crystallizes in the cubic Ia3 space group (a = 22.573(5) Å, V = 11502(4) Å(3)), with the Br(-) ion located on 3 site and molecule 1 on a 3-fold axis. The 6-fold, unprecedented octahedral coordination of the bromide anion generates an hexagonal three-dimensional network of Pa3 symmetry, as observed in the pyrite model structure, at variance with the usual, but lower-symmetry, rutile-type topology. In this complex system, the I centering gives rise to a 2-fold interpenetration of class Ia, while the cations and solvent molecules are found disordered within interconnected cavities. Another related cubic structure of comparable unit cell volume (space group Pa3̅, a = 22.4310(15) Å, V = 11286.2(13) Å(3)) is found with (1)2·(Et3S(+)I(-))." @default.
• W2324669492 created "2016-06-24" @default.
• W2324669492 creator A5029950669 @default.
• W2324669492 creator A5042248283 @default.
• W2324669492 creator A5063749323 @default.
• W2324669492 date "2013-04-10" @default.
• W2324669492 modified "2023-10-18" @default.
• W2324669492 title "Expanded Halogen-Bonded Anion Organic Networks with Star-Shaped Iodoethynyl-Substituted Molecules: From Corrugated 2D Hexagonal Lattices to Pyrite-Type 2-Fold Interpenetrated Cubic Lattices" @default.
• W2324669492 cites W149586247 @default.
• W2324669492 cites W1548914255 @default.
• W2324669492 cites W1969635440 @default.
• W2324669492 cites W1971413830 @default.
• W2324669492 cites W1972646318 @default.
• W2324669492 cites W1973293725 @default.
• W2324669492 cites W1975783842 @default.
• W2324669492 cites W1976533201 @default.
• W2324669492 cites W1977143222 @default.
• W2324669492 cites W1978659336 @default.
• W2324669492 cites W1979243460 @default.
• W2324669492 cites W1981338080 @default.
• W2324669492 cites W1981687672 @default.
• W2324669492 cites W1991506892 @default.
• W2324669492 cites W1996973977 @default.
• W2324669492 cites W1999937609 @default.
• W2324669492 cites W2003174483 @default.
• W2324669492 cites W2006648558 @default.
• W2324669492 cites W2007819793 @default.
• W2324669492 cites W2015176018 @default.
• W2324669492 cites W2016389238 @default.
• W2324669492 cites W2018553833 @default.
• W2324669492 cites W2019008092 @default.
• W2324669492 cites W2019210900 @default.
• W2324669492 cites W2019410105 @default.
• W2324669492 cites W2024114997 @default.
• W2324669492 cites W2024472474 @default.
• W2324669492 cites W2025127524 @default.
• W2324669492 cites W2026097027 @default.
• W2324669492 cites W2028578798 @default.
• W2324669492 cites W2035065226 @default.
• W2324669492 cites W2035206450 @default.
• W2324669492 cites W2036672535 @default.
• W2324669492 cites W2047364144 @default.
• W2324669492 cites W2051179984 @default.
• W2324669492 cites W2053308785 @default.
• W2324669492 cites W2055040078 @default.
• W2324669492 cites W2060998083 @default.
• W2324669492 cites W2063200470 @default.
• W2324669492 cites W2063334178 @default.
• W2324669492 cites W2069257555 @default.
• W2324669492 cites W2075627699 @default.
• W2324669492 cites W2078456005 @default.
• W2324669492 cites W2082269735 @default.
• W2324669492 cites W2086894471 @default.
• W2324669492 cites W2087089429 @default.
• W2324669492 cites W2087178879 @default.
• W2324669492 cites W2092575375 @default.
• W2324669492 cites W2103519974 @default.
• W2324669492 cites W2104535013 @default.
• W2324669492 cites W2108000066 @default.
• W2324669492 cites W2114462662 @default.
• W2324669492 cites W2122923591 @default.
• W2324669492 cites W2128123915 @default.
• W2324669492 cites W2133413783 @default.
• W2324669492 cites W2139620616 @default.
• W2324669492 cites W2144175099 @default.
• W2324669492 cites W2145270981 @default.
• W2324669492 cites W2147758158 @default.
• W2324669492 cites W2149565357 @default.
• W2324669492 cites W2151037107 @default.
• W2324669492 cites W2151183577 @default.
• W2324669492 cites W2158202410 @default.
• W2324669492 cites W2158744361 @default.
• W2324669492 cites W2161668046 @default.
• W2324669492 cites W2162618006 @default.
• W2324669492 cites W2164408025 @default.
• W2324669492 cites W2167562750 @default.
• W2324669492 cites W2169458432 @default.
• W2324669492 cites W2326425921 @default.
• W2324669492 cites W2511995840 @default.
• W2324669492 cites W2785888854 @default.
• W2324669492 cites W2886417674 @default.
• W2324669492 cites W2950580013 @default.
• W2324669492 cites W2951819386 @default.
• W2324669492 cites W4238674755 @default.
• W2324669492 cites W4253810815 @default.
• W2324669492 doi "https://doi.org/10.1021/ja400740v" @default.
• W2324669492 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23530604" @default.
• W2324669492 hasPublicationYear "2013" @default.
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