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• W2324708346 abstract "In the following article the coordination properties of a recently reported curcuminoid 9Accm (9Accm = 1,7-(di-9-anthracene)-1,6-heptadiene-3,5-dione) with ZnII are reported. Preparation, crystal structure, and fluorescence spectroscopic studies of [ZnII(9Accm)2(py)] (1) are presented, as well as preliminary AFM and confocal microscopy studies on graphite surfaces. Complex 1 is the first crystallographically characterized Zn–curcuminoid in the literature; the intrinsic features of the complex are contrasted with the free ligand, 9Accm, and [CuII(9Accm)2(py)] (2), a similar copper system, which has been recently described by us. It is shown that complex 1 exhibits a chelation enhancement of fluorescence (CHEF) and 2 a chelation enhancement of quenching (CHEQ) with respect to the fluorescence response of the free ligand, demonstrating the highly sensitive response of 9Accm versus these two metals. All studies are supported by density functional theory (DFT) calculations." @default.
• W2324708346 created "2016-06-24" @default.
• W2324708346 creator A5020153852 @default.
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• W2324708346 creator A5078676088 @default.
• W2324708346 date "2011-12-28" @default.
• W2324708346 modified "2023-10-15" @default.
• W2324708346 title "Crystal Structure, Fluorescence, and Nanostructuration Studies of the First Zn^II Anthracene-Based Curcuminoid" @default.
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• W2324708346 doi "https://doi.org/10.1021/ic201420d" @default.
• W2324708346 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22220749" @default.
• W2324708346 hasPublicationYear "2011" @default.
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