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- W2324812863 abstract "The Claisen rearrangement of some allyl naphthalen-1-yl ethers has been examined, together with methods for modification of the resulting 2-ally1 side chain. Isomerization of the C-allyl substituent to a prop-1-enyl group followed by ozonolysis gives a formyl derivative, while ozonolysis of a 2-(2-methylprop-2-enyl) moiety or mercuriation of a 2-(2-chloroprop-2-enyl) substituent leads to an acetonyl derivative. Treatment of phenols with iodine(I) acetate and an excess of silver(I) acetate gives 4-hydroxyaryl acetates, probably via dienone intermediates." @default.
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- W2324812863 date "1983-01-01" @default.
- W2324812863 modified "2023-09-27" @default.
- W2324812863 title "Experiments directed towards the synthesis of anthracyclinones. VII. Model studies with allyl naphthalenyl ethers" @default.
- W2324812863 doi "https://doi.org/10.1071/ch9830803" @default.
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