Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324813344> ?p ?o ?g. }
- W2324813344 endingPage "3213" @default.
- W2324813344 startingPage "3193" @default.
- W2324813344 abstract "The in-depth understanding of the kinetics and mechanism of conventional and reversible deactivation radical polymerization (RDRP) strategies requires efficient techniques to attain accurate rate coefficients of the individual reaction steps. Within the recently developed SP-PLP-EPR technique, pulsed-laser polymerization (PLP) induced by a laser single pulse (SP) is carried out in conjunction with highly time-resolved EPR detection of the type and the concentration of radicals. The method provides an unrivaled direct access to the measurement of chain-length-dependent termination and also of propagation rate. Even for systems where as a consequence of transfer reactions different types of radical species with distinctly different properties occur, a full kinetic analysis is within reach. The SP-PLP-EPR technique is also applicable toward the measurement of RDRP-related rate coefficients for reversible addition–fragmentation transfer (RAFT) polymerization, atom transfer radical polymerization (ATRP), and organometallic-mediated radical polymerization (OMRP). Investigations into the latter two polymerization strategies benefit from additionally applying UV/vis/NIR in conjunction with Mössbauer spectroscopy to monitor reactions of the metal catalyst." @default.
- W2324813344 created "2016-06-24" @default.
- W2324813344 creator A5002748535 @default.
- W2324813344 creator A5014443257 @default.
- W2324813344 creator A5055116080 @default.
- W2324813344 date "2016-03-30" @default.
- W2324813344 modified "2023-10-16" @default.
- W2324813344 title "Detailed Kinetic and Mechanistic Insight into Radical Polymerization by Spectroscopic Techniques" @default.
- W2324813344 cites W1498700437 @default.
- W2324813344 cites W1516536514 @default.
- W2324813344 cites W1519701368 @default.
- W2324813344 cites W1542953547 @default.
- W2324813344 cites W1549034645 @default.
- W2324813344 cites W1594177186 @default.
- W2324813344 cites W1912122088 @default.
- W2324813344 cites W1937803143 @default.
- W2324813344 cites W1941657305 @default.
- W2324813344 cites W1964892471 @default.
- W2324813344 cites W1965861022 @default.
- W2324813344 cites W1965983756 @default.
- W2324813344 cites W1966484500 @default.
- W2324813344 cites W1967866710 @default.
- W2324813344 cites W1968471547 @default.
- W2324813344 cites W1970543378 @default.
- W2324813344 cites W1970979329 @default.
- W2324813344 cites W1971294738 @default.
- W2324813344 cites W1972166525 @default.
- W2324813344 cites W1972400545 @default.
- W2324813344 cites W1974433644 @default.
- W2324813344 cites W1977394207 @default.
- W2324813344 cites W1977786455 @default.
- W2324813344 cites W1977944110 @default.
- W2324813344 cites W1978375504 @default.
- W2324813344 cites W1980934578 @default.
- W2324813344 cites W1981607600 @default.
- W2324813344 cites W1983234215 @default.
- W2324813344 cites W1987445563 @default.
- W2324813344 cites W1989159238 @default.
- W2324813344 cites W1991331281 @default.
- W2324813344 cites W1992062454 @default.
- W2324813344 cites W1993100556 @default.
- W2324813344 cites W1993752752 @default.
- W2324813344 cites W1994273716 @default.
- W2324813344 cites W1995234864 @default.
- W2324813344 cites W1995990618 @default.
- W2324813344 cites W1996726982 @default.
- W2324813344 cites W1998121154 @default.
- W2324813344 cites W1999215773 @default.
- W2324813344 cites W2000521135 @default.
- W2324813344 cites W2001878039 @default.
- W2324813344 cites W2002391756 @default.
- W2324813344 cites W2005293551 @default.
- W2324813344 cites W2006115982 @default.
- W2324813344 cites W2006312224 @default.
- W2324813344 cites W2006457861 @default.
- W2324813344 cites W2006699607 @default.
- W2324813344 cites W2008816032 @default.
- W2324813344 cites W2014445531 @default.
- W2324813344 cites W2016178901 @default.
- W2324813344 cites W2016797896 @default.
- W2324813344 cites W2019444028 @default.
- W2324813344 cites W2019890369 @default.
- W2324813344 cites W2021042092 @default.
- W2324813344 cites W2022355410 @default.
- W2324813344 cites W2023190589 @default.
- W2324813344 cites W2023991226 @default.
- W2324813344 cites W2024493356 @default.
- W2324813344 cites W2025231200 @default.
- W2324813344 cites W2027252204 @default.
- W2324813344 cites W2027840166 @default.
- W2324813344 cites W2031912582 @default.
- W2324813344 cites W2031994733 @default.
- W2324813344 cites W2033328940 @default.
- W2324813344 cites W2036333105 @default.
- W2324813344 cites W2038248035 @default.
- W2324813344 cites W2038487333 @default.
- W2324813344 cites W2039637179 @default.
- W2324813344 cites W2040744996 @default.
- W2324813344 cites W2044444337 @default.
- W2324813344 cites W2047210345 @default.
- W2324813344 cites W2048350307 @default.
- W2324813344 cites W2048896155 @default.
- W2324813344 cites W2049905118 @default.
- W2324813344 cites W2051746974 @default.
- W2324813344 cites W2053426108 @default.
- W2324813344 cites W2053898708 @default.
- W2324813344 cites W2054178986 @default.
- W2324813344 cites W2055032779 @default.
- W2324813344 cites W2056174926 @default.
- W2324813344 cites W2059253518 @default.
- W2324813344 cites W2060126960 @default.
- W2324813344 cites W2060444846 @default.
- W2324813344 cites W2060571716 @default.
- W2324813344 cites W2060979151 @default.
- W2324813344 cites W2061447113 @default.
- W2324813344 cites W2061682742 @default.
- W2324813344 cites W2062617337 @default.
- W2324813344 cites W2062642057 @default.