FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2324831966> ?p ?o ?g. }

• W2324831966 abstract "High-resolution laser excitation spectroscopy has been used to record the ÃE2-X̃A12 electronic transition of SrCH3 in a laser ablation/molecular jet source. Transitions arising from the K′=1←K″=0, K′=0←K″=1, and K′=2←K″=1 subbands have been observed and assigned. The data were modeled with E2 and A12 symmetric top Hamiltonian matrices in a Hund’s case (a) basis, using a least squares fitting program. Rotational and fine structure parameters for the ÃE2 state were determined. A comparison of the spin-orbit energy separation in the ÃE2 state to other strontium containing free radicals showed that the Jahn-Teller effect is negligible. The spin-rotation constants for the ÃE2 state were calculated using the pure precession model and were found to be in good agreement with the experimentally determined parameters. These calculations suggest that the ÃE2 state of SrCH3 is not entirely of p orbital character. The rotational constants were used to estimate the structural parameters of SrCH3 in the ÃE2 state. The strontium-carbon bond length was found to decrease by ∼0.006Å, and the hydrogen-carbon-hydrogen bond angle opened by ∼0.8° compared to the X̃A12 state, similar to the geometry changes observed for CaCH3." @default.
• W2324831966 created "2016-06-24" @default.
• W2324831966 creator A5033074939 @default.
• W2324831966 creator A5045053712 @default.
• W2324831966 creator A5056928928 @default.
• W2324831966 creator A5079805799 @default.
• W2324831966 date "2006-05-04" @default.
• W2324831966 modified "2023-09-23" @default.
• W2324831966 title "High-resolution laser excitation spectroscopy of the ÃE2-X̃A12 transition of SrCH3" @default.
• W2324831966 cites W1522715955 @default.
• W2324831966 cites W1676842191 @default.
• W2324831966 cites W1966112826 @default.
• W2324831966 cites W1966250839 @default.
• W2324831966 cites W1974302768 @default.
• W2324831966 cites W1991296128 @default.
• W2324831966 cites W1992940530 @default.
• W2324831966 cites W1994101905 @default.
• W2324831966 cites W1995709170 @default.
• W2324831966 cites W1996977861 @default.
• W2324831966 cites W1998474243 @default.
• W2324831966 cites W2008014708 @default.
• W2324831966 cites W2017740388 @default.
• W2324831966 cites W2018232596 @default.
• W2324831966 cites W2018382358 @default.
• W2324831966 cites W2040843911 @default.
• W2324831966 cites W2043351623 @default.
• W2324831966 cites W2044202476 @default.
• W2324831966 cites W2052986824 @default.
• W2324831966 cites W2056064268 @default.
• W2324831966 cites W2078524710 @default.
• W2324831966 cites W2085073182 @default.
• W2324831966 cites W2085942812 @default.
• W2324831966 cites W2086941827 @default.
• W2324831966 cites W2087347319 @default.
• W2324831966 cites W2116887893 @default.
• W2324831966 cites W2123899663 @default.
• W2324831966 cites W2136357637 @default.
• W2324831966 cites W2146406469 @default.
• W2324831966 cites W2149191047 @default.
• W2324831966 cites W2207312281 @default.
• W2324831966 cites W4242894417 @default.
• W2324831966 doi "https://doi.org/10.1063/1.2189236" @default.
• W2324831966 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16689573" @default.
• W2324831966 hasPublicationYear "2006" @default.
• W2324831966 type Work @default.
• W2324831966 sameAs 2324831966 @default.
• W2324831966 citedByCount "6" @default.
• W2324831966 countsByYear W23248319662016 @default.
• W2324831966 countsByYear W23248319662017 @default.
• W2324831966 countsByYear W23248319662021 @default.
• W2324831966 crossrefType "journal-article" @default.
• W2324831966 hasAuthorship W2324831966A5033074939 @default.
• W2324831966 hasAuthorship W2324831966A5045053712 @default.
• W2324831966 hasAuthorship W2324831966A5056928928 @default.
• W2324831966 hasAuthorship W2324831966A5079805799 @default.
• W2324831966 hasConcept C121332964 @default.
• W2324831966 hasConcept C167812310 @default.
• W2324831966 hasConcept C181500209 @default.
• W2324831966 hasConcept C184779094 @default.
• W2324831966 hasConcept C185592680 @default.
• W2324831966 hasConcept C21074235 @default.
• W2324831966 hasConcept C32891209 @default.
• W2324831966 hasConcept C41999313 @default.
• W2324831966 hasConcept C62520636 @default.
• W2324831966 hasConcept C83581075 @default.
• W2324831966 hasConceptScore W2324831966C121332964 @default.
• W2324831966 hasConceptScore W2324831966C167812310 @default.
• W2324831966 hasConceptScore W2324831966C181500209 @default.
• W2324831966 hasConceptScore W2324831966C184779094 @default.
• W2324831966 hasConceptScore W2324831966C185592680 @default.
• W2324831966 hasConceptScore W2324831966C21074235 @default.
• W2324831966 hasConceptScore W2324831966C32891209 @default.
• W2324831966 hasConceptScore W2324831966C41999313 @default.
• W2324831966 hasConceptScore W2324831966C62520636 @default.
• W2324831966 hasConceptScore W2324831966C83581075 @default.
• W2324831966 hasIssue "17" @default.
• W2324831966 hasLocation W23248319661 @default.
• W2324831966 hasLocation W23248319662 @default.
• W2324831966 hasOpenAccess W2324831966 @default.
• W2324831966 hasPrimaryLocation W23248319661 @default.
• W2324831966 hasRelatedWork W1964901514 @default.
• W2324831966 hasRelatedWork W2015653434 @default.
• W2324831966 hasRelatedWork W2017510390 @default.
• W2324831966 hasRelatedWork W2036639385 @default.
• W2324831966 hasRelatedWork W2039318747 @default.
• W2324831966 hasRelatedWork W2042595795 @default.
• W2324831966 hasRelatedWork W2047488268 @default.
• W2324831966 hasRelatedWork W2047905520 @default.
• W2324831966 hasRelatedWork W2131880765 @default.
• W2324831966 hasRelatedWork W2136225388 @default.
• W2324831966 hasVolume "124" @default.
• W2324831966 isParatext "false" @default.
• W2324831966 isRetracted "false" @default.
• W2324831966 magId "2324831966" @default.
• W2324831966 workType "article" @default.