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• W2324892372 endingPage "8217" @default.
• W2324892372 startingPage "8208" @default.
• W2324892372 abstract "Analysis of a monoclinic modification of Zr(CH2Ph)4 by single-crystal X-ray diffraction reveals that the bond angles Zr–CH2–Ph in this compound span a range of 25.1°, which is much larger than previously observed for the orthorhombic form (12.1°). In accord with this large range, density functional theory calculations demonstrate that little energy is required to perturb the Zr–CH2–Ph bond angles in this compound. Furthermore, density functional theory calculations on Me3ZrCH2Ph indicate that bending of the Zr–CH2–Ph moiety in the monobenzyl compound is also facile, thereby demonstrating that a benzyl ligand attached to zirconium is intrinsically flexible, such that its bending does not require a buffering effect involving another benzyl ligand." @default.
• W2324892372 created "2016-06-24" @default.
• W2324892372 creator A5064895632 @default.
• W2324892372 creator A5072093741 @default.
• W2324892372 creator A5083147441 @default.
• W2324892372 date "2012-11-09" @default.
• W2324892372 modified "2023-09-28" @default.
• W2324892372 title "Highly Variable Zr–CH₂–Ph Bond Angles in Tetrabenzylzirconium: Analysis of Benzyl Ligand Coordination Modes" @default.
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• W2324892372 doi "https://doi.org/10.1021/om300820b" @default.
• W2324892372 hasPublicationYear "2012" @default.
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