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• W2324957714 endingPage "8090" @default.
• W2324957714 startingPage "8083" @default.
• W2324957714 abstract "In order to determine the electronic factors that may affect the catalytic antioxidant activity of water-soluble metallocorroles a series of 10-aryl-5,15-pyridinium manganese(III) corroles was prepared. These complexes were examined regarding the effect of the C10 substituent on the MnIV/MnIII redox potentials, catalytic rate constants for decomposition of HOONO, prevention of tyrosine nitration, and superoxide dismutase activity. This structure–activity relationship investigation provides new insight regarding the mechanism by which manganese(III) corroles act as catalytic antioxidants. It also discloses the superiority of the C10-anysil-substituted complex in all examined aspects." @default.
• W2324957714 created "2016-06-24" @default.
• W2324957714 creator A5047448715 @default.
• W2324957714 creator A5080211133 @default.
• W2324957714 date "2012-07-18" @default.
• W2324957714 modified "2023-09-26" @default.
• W2324957714 title "Fine Tuning the Reactivity of Corrole-Based Catalytic Antioxidants" @default.
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• W2324957714 doi "https://doi.org/10.1021/ic300408s" @default.
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