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- W2324963899 abstract "Abstract Two new Ag(I)-saccharinate complexes, K[Ag(sac) 2 ] · H 2 O ( 1 ) and [Ag(sac)(ina)] · 1.5 H 2 O ( 2 ) (sac = saccharinate and ina = isonicotinamide), have been synthesized and characterized by elemental analyses, IR spectroscopy, thermal analysis and single crystal X-ray diffraction. The silver atoms adopt a linear AgN 2 geometry in each case defined by two sac ligands in 1 , and one sac and one ina ligand in 2 . In 1 , the anionic complex units are linked into a two-dimensional array by two potassium atoms, forming an eight-membered bimetallic ring and a K 2 O 10 potassium−oxygen cluster. Complex 2 shows rare (O—H) ··· Ag and (N—H) ··· Ag interactions. The molecules are connected by Ag ··· C sac (η 3 ) interactions involväing the saccharinate-phenyl rings." @default.
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- W2324963899 date "2012-07-24" @default.
- W2324963899 modified "2023-09-23" @default.
- W2324963899 title "Two photoluminescent silver(I) saccharinate complexes: The formation of a potassium-oxygen cluster, and Ag ··· π and (O—H) ··· Ag interactions" @default.
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- W2324963899 doi "https://doi.org/10.1524/zkri.2012.1520" @default.
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