Matches in SemOpenAlex for { <https://semopenalex.org/work/W2325094493> ?p ?o ?g. }
- W2325094493 endingPage "7809" @default.
- W2325094493 startingPage "7803" @default.
- W2325094493 abstract "Adsorption of 13C-enriched methanol in multiwalled carbon nanotubes (MWNTs) was systematically studied under well-controlled environment by 13C MAS NMR. The results of variable-pressure experiments indicate that the endohedral adsorption of methanol in carbon nanotubes (CNTs) is preferential over the exohedral adsorption. The exohedral adsorption does not occur until the endohedral adsorption saturates. The 13C chemical shift of endohedral methanol exhibits a large upfield shift due to the strong spatial diamagnetic shielding effect induced by the delocalized electrons of nanotubes under the influence of external magnetic field. The exohedral methanol is also shielded, but to a lesser extent. DFT calculations support these experimental results. The 13C spin–lattice relaxation times, T1, of endohedral and exohedral methanol were also measured, and they have different vapor pressure dependence at room temperature. Furthermore, variable-temperature experiments suggest that methanol molecules inside CNTs may form a layered structure at low temperature with one layer close to the wall and the second layer near the center of the nanotubes." @default.
- W2325094493 created "2016-06-24" @default.
- W2325094493 creator A5003959033 @default.
- W2325094493 creator A5020325868 @default.
- W2325094493 creator A5039096982 @default.
- W2325094493 creator A5045204358 @default.
- W2325094493 creator A5070260505 @default.
- W2325094493 creator A5075748581 @default.
- W2325094493 date "2012-03-28" @default.
- W2325094493 modified "2023-10-17" @default.
- W2325094493 title "NMR Study of Preferential Endohedral Adsorption of Methanol in Multiwalled Carbon Nanotubes" @default.
- W2325094493 cites W1964831190 @default.
- W2325094493 cites W1967136881 @default.
- W2325094493 cites W1972612546 @default.
- W2325094493 cites W1973749596 @default.
- W2325094493 cites W1981172896 @default.
- W2325094493 cites W1983085710 @default.
- W2325094493 cites W1983109197 @default.
- W2325094493 cites W1985488514 @default.
- W2325094493 cites W1986465188 @default.
- W2325094493 cites W1988741517 @default.
- W2325094493 cites W1991064413 @default.
- W2325094493 cites W1995573523 @default.
- W2325094493 cites W2001901080 @default.
- W2325094493 cites W2015830992 @default.
- W2325094493 cites W2017542804 @default.
- W2325094493 cites W2017916950 @default.
- W2325094493 cites W2019390480 @default.
- W2325094493 cites W2020199085 @default.
- W2325094493 cites W2022565432 @default.
- W2325094493 cites W2022696619 @default.
- W2325094493 cites W2022916017 @default.
- W2325094493 cites W2023178738 @default.
- W2325094493 cites W2024005665 @default.
- W2325094493 cites W2028440884 @default.
- W2325094493 cites W2030937795 @default.
- W2325094493 cites W2031293469 @default.
- W2325094493 cites W2032743295 @default.
- W2325094493 cites W2040028571 @default.
- W2325094493 cites W2046478481 @default.
- W2325094493 cites W2053446906 @default.
- W2325094493 cites W2059477355 @default.
- W2325094493 cites W2065042378 @default.
- W2325094493 cites W2071285271 @default.
- W2325094493 cites W2073716652 @default.
- W2325094493 cites W2076168636 @default.
- W2325094493 cites W2082954570 @default.
- W2325094493 cites W2084277778 @default.
- W2325094493 cites W2084619794 @default.
- W2325094493 cites W2085017152 @default.
- W2325094493 cites W2086766048 @default.
- W2325094493 cites W2095883173 @default.
- W2325094493 cites W2111705896 @default.
- W2325094493 cites W2124508569 @default.
- W2325094493 cites W2138872642 @default.
- W2325094493 cites W2149027818 @default.
- W2325094493 cites W2150697053 @default.
- W2325094493 cites W2151201914 @default.
- W2325094493 cites W2156115804 @default.
- W2325094493 cites W2168460700 @default.
- W2325094493 doi "https://doi.org/10.1021/jp300138x" @default.
- W2325094493 hasPublicationYear "2012" @default.
- W2325094493 type Work @default.
- W2325094493 sameAs 2325094493 @default.
- W2325094493 citedByCount "24" @default.
- W2325094493 countsByYear W23250944932013 @default.
- W2325094493 countsByYear W23250944932014 @default.
- W2325094493 countsByYear W23250944932015 @default.
- W2325094493 countsByYear W23250944932016 @default.
- W2325094493 countsByYear W23250944932017 @default.
- W2325094493 countsByYear W23250944932019 @default.
- W2325094493 countsByYear W23250944932020 @default.
- W2325094493 countsByYear W23250944932021 @default.
- W2325094493 countsByYear W23250944932023 @default.
- W2325094493 crossrefType "journal-article" @default.
- W2325094493 hasAuthorship W2325094493A5003959033 @default.
- W2325094493 hasAuthorship W2325094493A5020325868 @default.
- W2325094493 hasAuthorship W2325094493A5039096982 @default.
- W2325094493 hasAuthorship W2325094493A5045204358 @default.
- W2325094493 hasAuthorship W2325094493A5070260505 @default.
- W2325094493 hasAuthorship W2325094493A5075748581 @default.
- W2325094493 hasConcept C111429119 @default.
- W2325094493 hasConcept C115260700 @default.
- W2325094493 hasConcept C121332964 @default.
- W2325094493 hasConcept C147597530 @default.
- W2325094493 hasConcept C147789679 @default.
- W2325094493 hasConcept C150394285 @default.
- W2325094493 hasConcept C159467904 @default.
- W2325094493 hasConcept C171250308 @default.
- W2325094493 hasConcept C178790620 @default.
- W2325094493 hasConcept C185592680 @default.
- W2325094493 hasConcept C192562407 @default.
- W2325094493 hasConcept C2777619693 @default.
- W2325094493 hasConcept C2779607525 @default.
- W2325094493 hasConcept C513720949 @default.
- W2325094493 hasConcept C59593255 @default.
- W2325094493 hasConcept C62520636 @default.
- W2325094493 hasConcept C70050531 @default.