FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2325133903> ?p ?o ?g. }

• W2325133903 endingPage "9045" @default.
• W2325133903 startingPage "9040" @default.
• W2325133903 abstract "The effect of main chain stiffness and side chain flexibility on the elastic modulus and glass transition temperature (Tg) of thin polymer films is investigated using nontraditional polymers formed from 5-(2-phenylethylnorbornene). Depending on the polymerization route chosen, the resulting polymer backbone is comprised of either bicyclic (norbornyl) units, which leads to a relatively rigid polymer with a high bulk Tg, or monocyclic (cyclopentyl) units, which leads to a more flexible structure with a lower bulk Tg. The modulus and Tg of the rigid bicyclic polymer are thickness independent down to <10 nm, whereas the modulus of the more flexible monocyclic polymer decreases with decreasing thickness. By hydrogenation of the pendant phenyl ring to the cyclohexyl counterpart, we illustrate that minor changes in the relative flexibility of the side chain do not impact the observed thin film behavior. To further support our hypothesis that main chain stiffness (persistence length) plays a central role in confinement-induced changes in physical properties, a series of arylate/phosphonate copolymers, where the addition of phosphonate groups decreases the overall stiffness of the polymer backbone, are also examined. Similar to the polynorbornenes, the poly(arylate-co-phosphonate) polymers exhibit more pronounced thickness-dependent properties as the stiffness of the backbone decreases. We believe based upon our results that examination of chain flexibility in the thin film glass community for future works would be extremely useful in elucidating the physical origins of observed phenomena." @default.
• W2325133903 created "2016-06-24" @default.
• W2325133903 creator A5004025863 @default.
• W2325133903 creator A5023849323 @default.
• W2325133903 creator A5030285876 @default.
• W2325133903 creator A5030929672 @default.
• W2325133903 creator A5043777280 @default.
• W2325133903 creator A5065260816 @default.
• W2325133903 creator A5080206851 @default.
• W2325133903 creator A5087864043 @default.
• W2325133903 date "2011-10-25" @default.
• W2325133903 modified "2023-09-30" @default.
• W2325133903 title "Influence of Chain Stiffness on Thermal and Mechanical Properties of Polymer Thin Films" @default.
• W2325133903 cites W1548725715 @default.
• W2325133903 cites W1568546143 @default.
• W2325133903 cites W1617047979 @default.
• W2325133903 cites W1973317919 @default.
• W2325133903 cites W1975575453 @default.
• W2325133903 cites W1979493895 @default.
• W2325133903 cites W1983067422 @default.
• W2325133903 cites W1987441176 @default.
• W2325133903 cites W1988385446 @default.
• W2325133903 cites W1990284496 @default.
• W2325133903 cites W1991258067 @default.
• W2325133903 cites W1991533374 @default.
• W2325133903 cites W1995671600 @default.
• W2325133903 cites W1998906630 @default.
• W2325133903 cites W2001381557 @default.
• W2325133903 cites W2002246001 @default.
• W2325133903 cites W2006498334 @default.
• W2325133903 cites W2013334342 @default.
• W2325133903 cites W2017771574 @default.
• W2325133903 cites W2019893222 @default.
• W2325133903 cites W2022769068 @default.
• W2325133903 cites W2024845971 @default.
• W2325133903 cites W2026578026 @default.
• W2325133903 cites W2027350181 @default.
• W2325133903 cites W2029422848 @default.
• W2325133903 cites W2038222689 @default.
• W2325133903 cites W2039660764 @default.
• W2325133903 cites W2040172162 @default.
• W2325133903 cites W2044151926 @default.
• W2325133903 cites W2045016739 @default.
• W2325133903 cites W2046163750 @default.
• W2325133903 cites W2046239468 @default.
• W2325133903 cites W2049941660 @default.
• W2325133903 cites W2054803909 @default.
• W2325133903 cites W2055597640 @default.
• W2325133903 cites W2068936354 @default.
• W2325133903 cites W2070823337 @default.
• W2325133903 cites W2072881778 @default.
• W2325133903 cites W2075310089 @default.
• W2325133903 cites W2085503899 @default.
• W2325133903 cites W2088395478 @default.
• W2325133903 cites W2090164340 @default.
• W2325133903 cites W2094869367 @default.
• W2325133903 cites W2118778340 @default.
• W2325133903 cites W2120532563 @default.
• W2325133903 cites W2129097895 @default.
• W2325133903 cites W2141075684 @default.
• W2325133903 cites W2155282152 @default.
• W2325133903 cites W2162053762 @default.
• W2325133903 cites W2962978790 @default.
• W2325133903 cites W2087576219 @default.
• W2325133903 doi "https://doi.org/10.1021/ma201482b" @default.
• W2325133903 hasPublicationYear "2011" @default.
• W2325133903 type Work @default.
• W2325133903 sameAs 2325133903 @default.
• W2325133903 citedByCount "79" @default.
• W2325133903 countsByYear W23251339032012 @default.
• W2325133903 countsByYear W23251339032013 @default.
• W2325133903 countsByYear W23251339032014 @default.
• W2325133903 countsByYear W23251339032015 @default.
• W2325133903 countsByYear W23251339032016 @default.
• W2325133903 countsByYear W23251339032017 @default.
• W2325133903 countsByYear W23251339032018 @default.
• W2325133903 countsByYear W23251339032019 @default.
• W2325133903 countsByYear W23251339032020 @default.
• W2325133903 countsByYear W23251339032021 @default.
• W2325133903 countsByYear W23251339032022 @default.
• W2325133903 countsByYear W23251339032023 @default.
• W2325133903 crossrefType "journal-article" @default.
• W2325133903 hasAuthorship W2325133903A5004025863 @default.
• W2325133903 hasAuthorship W2325133903A5023849323 @default.
• W2325133903 hasAuthorship W2325133903A5030285876 @default.
• W2325133903 hasAuthorship W2325133903A5030929672 @default.
• W2325133903 hasAuthorship W2325133903A5043777280 @default.
• W2325133903 hasAuthorship W2325133903A5065260816 @default.
• W2325133903 hasAuthorship W2325133903A5080206851 @default.
• W2325133903 hasAuthorship W2325133903A5087864043 @default.
• W2325133903 hasConcept C122865956 @default.
• W2325133903 hasConcept C15920480 @default.
• W2325133903 hasConcept C159985019 @default.
• W2325133903 hasConcept C171250308 @default.
• W2325133903 hasConcept C178790620 @default.
• W2325133903 hasConcept C185592680 @default.
• W2325133903 hasConcept C188027245 @default.
• W2325133903 hasConcept C19067145 @default.

• next