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- W2325192010 abstract "H-bonding activation in the regioselective acetylation of vicinal and 1,3-diols is presented. Herein, the acetylation of the hydroxyl group with acetic anhydride can be activated by the formation of H-bonds between the hydroxyl group and anions. The reaction exhibits high regioselectivity when a catalytic amount of tetrabutylammonium acetate is employed. Mechanistic studies indicated that acetate anion forms dual H-bonding complexes with the diol, which facilitates the subsequent regioselective monoacetylation." @default.
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- W2325192010 date "2013-11-05" @default.
- W2325192010 modified "2023-10-12" @default.
- W2325192010 title "H-Bonding Activation in Highly Regioselective Acetylation of Diols" @default.
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- W2325192010 doi "https://doi.org/10.1021/jo402036u" @default.
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