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• W2325200154 abstract "Abstract A rare example of coordination at the amino group of NH 2 pym (2‐aminopyrimidine) relevant to NH activation is described that leads to a novel Ag I –imide 3D metal–organic framework (MOF). The coordination of Ag I to NH 2 pym produced an electron‐withdrawing effect and thus increased its acidity, which facilitated the NH activation and the subsequent formation of the Ag–imide bond. A cooperative metalation/deprotonation process for the NH activation of NH 2 pym is suggested. Interestingly, photoluminescence of 1 is switched on at the low temperature of 77 K." @default.
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• W2325200154 date "2013-11-14" @default.
• W2325200154 modified "2023-10-18" @default.
• W2325200154 title "Unusual NH Activation of 2-Aminopyrimidine: Supramolecular Assembly into an Ag^IMetal-Organic Framework" @default.
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• W2325200154 doi "https://doi.org/10.1002/asia.201301244" @default.
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