Matches in SemOpenAlex for { <https://semopenalex.org/work/W2325205412> ?p ?o ?g. }
- W2325205412 endingPage "2109" @default.
- W2325205412 startingPage "2104" @default.
- W2325205412 abstract "We report intermolecular electron transfer between 2,2,6,6-tetramethylpiperidin-1-oxoammonium tetrafluoroborate (TEMPO+BF4–) and thiol-stabilized [Au25(SC2H4Ph)18]−TOA+ (abbreviated as Au25–) nanoclusters. The TEMPO+ cations are generated by single electron oxidation of piperidine aminoxyl radical TEMPO (2,2,6,6-tetramethylpiperidinyl-oxy). Cyclic voltammetry (CV) and electron spin resonance (ESR) explicitly indicate that two consecutive single-electron transfer reactions occur between TEMPO+ cations and Au25– nanoclusters. Nuclear magnetic resonance (1H NMR) analysis demonstrates that the methylene proton resonances of the thiolate ligands can also be used to monitor the redox process. UV–vis spectroscopic analysis reveals the changes in the absorption peaks of Au25 nanoclusters upon consecutive single-electron transfers between the nanoclusters and TEMPO+ cations. The ease of control over the redox process involving TEMPO+ allows the preparation of pure Au25(SC2H4Ph)18+ nanoclusters. The interesting electron-donating properties of Au25(SR)18 clusters may find some promising applications in future studies." @default.
- W2325205412 created "2016-06-24" @default.
- W2325205412 creator A5018678606 @default.
- W2325205412 creator A5020512076 @default.
- W2325205412 creator A5072746712 @default.
- W2325205412 creator A5078150685 @default.
- W2325205412 creator A5087024442 @default.
- W2325205412 date "2011-08-09" @default.
- W2325205412 modified "2023-10-03" @default.
- W2325205412 title "Electron Transfer between [Au<sub>25</sub>(SC<sub>2</sub>H<sub>4</sub>Ph)<sub>18</sub>]<sup>−</sup>TOA<sup>+</sup> and Oxoammonium Cations" @default.
- W2325205412 cites W1454716643 @default.
- W2325205412 cites W1964993191 @default.
- W2325205412 cites W1972213899 @default.
- W2325205412 cites W1973153517 @default.
- W2325205412 cites W1973961500 @default.
- W2325205412 cites W1977035587 @default.
- W2325205412 cites W1980939315 @default.
- W2325205412 cites W1982437634 @default.
- W2325205412 cites W1983711072 @default.
- W2325205412 cites W1983735836 @default.
- W2325205412 cites W1984379455 @default.
- W2325205412 cites W1985183219 @default.
- W2325205412 cites W1993779520 @default.
- W2325205412 cites W1994897760 @default.
- W2325205412 cites W1995465526 @default.
- W2325205412 cites W1996282367 @default.
- W2325205412 cites W2001551125 @default.
- W2325205412 cites W2003031243 @default.
- W2325205412 cites W2006019035 @default.
- W2325205412 cites W2011703668 @default.
- W2325205412 cites W2012815156 @default.
- W2325205412 cites W2012828083 @default.
- W2325205412 cites W2014008281 @default.
- W2325205412 cites W2016807138 @default.
- W2325205412 cites W2016959916 @default.
- W2325205412 cites W2017744970 @default.
- W2325205412 cites W2024854660 @default.
- W2325205412 cites W2030561760 @default.
- W2325205412 cites W2032076075 @default.
- W2325205412 cites W2034183695 @default.
- W2325205412 cites W2039767749 @default.
- W2325205412 cites W2044701233 @default.
- W2325205412 cites W2054273170 @default.
- W2325205412 cites W2059427804 @default.
- W2325205412 cites W2062267147 @default.
- W2325205412 cites W2063439322 @default.
- W2325205412 cites W2065084192 @default.
- W2325205412 cites W2065675356 @default.
- W2325205412 cites W2066286007 @default.
- W2325205412 cites W2066673480 @default.
- W2325205412 cites W2069807403 @default.
- W2325205412 cites W2074013888 @default.
- W2325205412 cites W2075131774 @default.
- W2325205412 cites W2082572228 @default.
- W2325205412 cites W2090046309 @default.
- W2325205412 cites W2118724333 @default.
- W2325205412 cites W2131123594 @default.
- W2325205412 cites W2132314137 @default.
- W2325205412 cites W2135097783 @default.
- W2325205412 cites W2140203159 @default.
- W2325205412 cites W2141686621 @default.
- W2325205412 cites W2151633590 @default.
- W2325205412 cites W2154827461 @default.
- W2325205412 cites W2158577673 @default.
- W2325205412 cites W2312658005 @default.
- W2325205412 cites W2312760481 @default.
- W2325205412 cites W2315282237 @default.
- W2325205412 cites W2315578735 @default.
- W2325205412 cites W2317068287 @default.
- W2325205412 cites W2317968805 @default.
- W2325205412 cites W2329132121 @default.
- W2325205412 cites W2335148374 @default.
- W2325205412 doi "https://doi.org/10.1021/jz200925h" @default.
- W2325205412 hasPublicationYear "2011" @default.
- W2325205412 type Work @default.
- W2325205412 sameAs 2325205412 @default.
- W2325205412 citedByCount "68" @default.
- W2325205412 countsByYear W23252054122012 @default.
- W2325205412 countsByYear W23252054122013 @default.
- W2325205412 countsByYear W23252054122014 @default.
- W2325205412 countsByYear W23252054122015 @default.
- W2325205412 countsByYear W23252054122016 @default.
- W2325205412 countsByYear W23252054122017 @default.
- W2325205412 countsByYear W23252054122018 @default.
- W2325205412 countsByYear W23252054122019 @default.
- W2325205412 countsByYear W23252054122020 @default.
- W2325205412 countsByYear W23252054122022 @default.
- W2325205412 countsByYear W23252054122023 @default.
- W2325205412 crossrefType "journal-article" @default.
- W2325205412 hasAuthorship W2325205412A5018678606 @default.
- W2325205412 hasAuthorship W2325205412A5020512076 @default.
- W2325205412 hasAuthorship W2325205412A5072746712 @default.
- W2325205412 hasAuthorship W2325205412A5078150685 @default.
- W2325205412 hasAuthorship W2325205412A5087024442 @default.
- W2325205412 hasConcept C113196181 @default.
- W2325205412 hasConcept C121332964 @default.
- W2325205412 hasConcept C123669783 @default.
- W2325205412 hasConcept C139210041 @default.