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- W2325344150 startingPage "584" @default.
- W2325344150 abstract "一般式 N(cH3)2+(cH2)N(ch3) において(n,m)；(2,2),(6,5),(8,8),(10,10)のIoneneを合成し,これをマトリックスとする。7,7,8,8-テトラシァノキノジメタン(CQ)塩の比抵抗(p),電導の活性化エネルギー(Ea)を測定した。Simple saltはイオン席間隔がメチレン数にして6までは,メチレン数の増加とともにp, Eaが増加するが,(8,8),(10,10)-lonene-CQでは(6,6)-lonene-CQにくらべ小さくなる。結局,電導性とイオン席間隔の相関は(2,5)-lonene-CQから(6,6)-lonene-CQまで認められる。そして,CQをとり込みその電導性に影響を与えるIoneneの高分子マトリックスとしての効果は(6,5)-loneneが一番大きく,添加比((中性CQ)/[CQアニオンラジカル])=1.0のcomplex saltでは,p；77 cm,Ea；0,14 eVとなる。" @default.
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- W2325344150 date "1974-01-01" @default.
- W2325344150 modified "2023-09-25" @default.
- W2325344150 title "Relation of Electric Conductivity and Interval between Ionlc Sites in 7, 7, 8, 8-Tetracyanoquinodimethane Salts of Poly(N-alkylene, N, N-dimethylammonium)" @default.
- W2325344150 doi "https://doi.org/10.1246/nikkashi.1974.584" @default.
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