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- W2325476076 abstract "Single crystals of the new compound CuHo 2 [B 2 O 5 ] 2 were obtained by using a B 2 O 3 flux technique with CuO and Ho 2 O 3 at 1050 °C. X-ray investigations on single crystals led to the space group P 2 1 /c (Nr. 14) with lattice parameters a = 454.3(2); b = 726.0(4); c = 936.0(5) pm; β = 90.77(1)°; Z = 2. The compound is isotypic to CuTb 2 [B 2 O 5 ] 2 as well as to the gadolinite structure (FeY 2 [BeSiO 5 ] 2 ). The structure exhibits layer-like ∞ 2 [B 2 O 5 ] 4- , a two-dimensional anion consisting of edge sharing BO 4 -tetrahedra, which form four- and eight-membered rings. The layers are connected by elongated CuO 6 -octahedra and slightly distorted tetragonal LnO 8 -antiprisms." @default.
- W2325476076 created "2016-06-24" @default.
- W2325476076 creator A5049305436 @default.
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- W2325476076 date "1998-01-01" @default.
- W2325476076 modified "2023-10-18" @default.
- W2325476076 title "CuHo<sub>2</sub>[B<sub>2</sub>O<sub>5</sub>]<sub>2</sub>: Ein unerwarteter Strukturtyp in der Reihe der Kupferlanthanoidborate / CuHo<sub>2</sub>[B<sub>2</sub>O<sub>5</sub>]<sub>2</sub>: An Unexpected Structure Type in the Series of Copper Lanthanoid Borates" @default.
- W2325476076 doi "https://doi.org/10.1515/znb-1998-0103" @default.
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