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• W2325605733 abstract "Abstract We have performed Mossbauer measurements on oriented powders of 57Fe-doped La2−xSrxCuO4 (x=0 and 0.2 ) and 57Co-doped La2CuO4. We find that the main axis OZ of the 57Fe electric field gradient in the series lies at an angle β=26°±5° with respect to the crystal c axis, which is much less than recently published values. Our data were corrected for a fraction of unoriented crystallites, which we find to be systematically present, but which was unsuspected in previous experiments. We describe a convenient X-ray examination procedure for detecting and evaluating the unoriented fraction. We discuss possible origins of the angle β and we examine the relative disposition of the direction of c, OZ and of the hyperfine field on 57Fe in La2CuO 4 below TN. We also consider the influence of the oxygen stoichiometry on the symmetry at the Fe site." @default.
• W2325605733 created "2016-06-24" @default.
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• W2325605733 date "1992-01-01" @default.
• W2325605733 modified "2023-10-13" @default.
• W2325605733 title "57Fe Mössbauer absorption and emission spectroscopy and X-ray measurements in oriented crystallites of La2−xSrxCuO4" @default.
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• W2325605733 doi "https://doi.org/10.1016/0921-4534(92)90613-h" @default.
• W2325605733 hasPublicationYear "1992" @default.
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