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- W2325612504 abstract "An aryl Grignard reagent in the presence of mesityl iodide converts an allylic C–H bond of a cycloalkene or an allylbenzene derivative into a C–C bond in the presence of a catalytic amount of Fe(acac)3 and a diphosphine ligand at 0 °C. The stereo- and regioselectivity of the reaction, together with deuterium labeling experiments, suggest that C–H bond activation is the slow step in the catalytic cycle preceding the formation of an allyliron intermediate." @default.
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- W2325612504 date "2013-01-22" @default.
- W2325612504 modified "2023-10-18" @default.
- W2325612504 title "Iron-Catalyzed Allylic Arylation of Olefins via C(sp<sup>3</sup>)–H Activation under Mild Conditions" @default.
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- W2325612504 doi "https://doi.org/10.1021/ol400056z" @default.
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