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- W2325641857 abstract "Metalation of 6,13,20,21-tetrakis(4-methylphenyl)-22H-tribenzo[14]triphyrin(2.1.1) with PtCl2 gave a platinum(II) complex having a square-planar coordination structure with two pyrrolic nitrogen atoms and two chloride ions, with a saddle-shaped macrocycle. This platinum(II) complex was easily oxidized by air to an octahedral platinum(IV) complex coordinated by three pyrrolic nitrogen atoms as a tridentate monoanionic cyclic ligand and three chloride ions. When platinum(II) triphyrin was crystallized in air, an oxygen atom was incorporated between two α-carbon atoms of the pyrroles as an oxygen bridge to intercept the 14π aromatic system." @default.
- W2325641857 created "2016-06-24" @default.
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- W2325641857 date "2013-02-04" @default.
- W2325641857 modified "2023-09-25" @default.
- W2325641857 title "Synthesis and Characterization of New Platinum(II) and Platinum(IV) Triphyrin Complexes" @default.
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- W2325641857 doi "https://doi.org/10.1021/ic302624h" @default.
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