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- W2325674568 abstract "(La${}_{2/3}$Ca${}_{1/3}$MnO${}_{3}$)${}_{n}$/(BaTiO${}_{3}$)${}_{m}$ (LCMO${}_{n}$/BTO${}_{m}$) superlattices on MgO and SrTiO${}_{3}$ substrates with different layer thicknesses ($n$ $=$ 10, 38, 40 and $m$ $=$ 5, 18, 20) have been grown by metal organic aerosol deposition (MAD) and have been fully characterized down to the atomic scale to study the interface characteristics. Scanning transmission electron microscopy combined with spatially resolved electron energy-loss spectroscopy provides clear evidence for the existence of atomically sharp interfaces in MAD grown films, which exhibit epitaxial growth conditions, a uniform normal strain, and a fully oxidized state. Below a critical layer thickness the LCMO structure is found to change from the bulk Pnma symmetry to a pseudocubic $R$$overline{3}$$c$ symmetry. An atomically flat interface reconstruction consisting of a single Ca-rich atomic layer is observed on the compressively strained BTO on LCMO interface, which is thought to partially neutralize the total charge from the alternating polar atomic layers in LCMO as well as relieving strain at the interface. No interface reconstruction is observed at the tensile strained LCMO on BTO interface." @default.
- W2325674568 created "2016-06-24" @default.
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- W2325674568 date "2013-01-22" @default.
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- W2325674568 title "Structural phase transition and spontaneous interface reconstruction in La<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mrow><mml:mn>2</mml:mn><mml:mo>/</mml:mo><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:math>Ca<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mrow><mml:mn>1</mml:mn><mml:mo>/</mml:mo><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:math>MnO<mml:math xmlns:mml=http://www.w3…" @default.
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- W2325674568 doi "https://doi.org/10.1103/physrevb.87.035418" @default.
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