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- W2325751489 abstract "The α-dicarbonylmonooximes 1 and 11 do not react as simple “CH-acidic-compounds” in the Mannich condensation. In a concerted reaction with aminals in absolute dioxane they give rise to the products 4a - e and 12a - e with better practicability and much higher yields compared with the conventional method. The Mannich bases with a cyclic amine part show in the dehydrogenation, using mercury-EDTA, a neighbouring group participation of the oxime in type 4 and of the oxime or amide function in 12 yielding cyclized products. For the reaction a plausible mechanism is proposed." @default.
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- W2325751489 date "1999-05-01" @default.
- W2325751489 modified "2023-10-14" @default.
- W2325751489 title "α-Dicarbonylmonoxime als Nucleophile und Nachbargruppen / α-Dicarbonylmonoximes as Nucleophiles and Neighbour Groups" @default.
- W2325751489 doi "https://doi.org/10.1515/znb-1999-0511" @default.
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