FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2325851421> ?p ?o ?g. }

• W2325851421 endingPage "11076" @default.
• W2325851421 startingPage "11069" @default.
• W2325851421 abstract "The complex [Ag(2)(PhPPy(2))(2)(NCCH(3))(2)](ClO(4))(2) [PhPPy(2) = bis(2-pyridyl)phenylphosphine] reacts with NH(4)Cl to form an insoluble one-dimensional polymer of the type (MMX)(n), {[Ag(2)(PhPPy(2))(2)Cl](ClO(4))}(n). The binuclear unit, Ag(2)(PhPPy(2))(2)(2+), exhibits two PhPPy(2) tridentate ligands bridging the two Ag atoms in a head-to-tail fashion with C(2h) symmetry, and the Ag···Ag distance [3.0942(11) Å, X-ray] suggests argentophilic interactions. Each Ag center adopts a distorted trigonal-bipyramidal geometry, coordinated by one P atom and two pyridyl arms at the equatorial positions and interacting with one Cl ion and one Ag ion at the axial positions. The short Ag-Cl bond length [2.5791(7) Å] indicates the presence of some covalent character. The solid-state absorption bands spread all the way to 600 nm have been interpreted by means of density functional theory (DFT) and time-dependent DFT (B3LYP), and the lowest-energy excited states are assigned to metal/halide-to-pyridyl charge transfer, consistent with the d(10) electronic configuration of Ag. The calculated oscillator strengths are low because of the poor molecular orbital overlaps in the charge-transfer components. The novel material exhibits a luminescence band centered at about ∼520 nm." @default.
• W2325851421 created "2016-06-24" @default.
• W2325851421 creator A5005815538 @default.
• W2325851421 creator A5034849353 @default.
• W2325851421 creator A5059107732 @default.
• W2325851421 creator A5069680336 @default.
• W2325851421 creator A5077289752 @default.
• W2325851421 date "2010-11-10" @default.
• W2325851421 modified "2023-10-06" @default.
• W2325851421 title "First Halogen Anion-Bridged (MMX)_<i>n</i>-Type One-Dimensional Coordination Polymer Built upon d¹⁰−d¹⁰ Dimers" @default.
• W2325851421 cites W1965272987 @default.
• W2325851421 cites W1970148666 @default.
• W2325851421 cites W1971933924 @default.
• W2325851421 cites W1976554132 @default.
• W2325851421 cites W1978967144 @default.
• W2325851421 cites W1982742013 @default.
• W2325851421 cites W1984614201 @default.
• W2325851421 cites W1988769516 @default.
• W2325851421 cites W1992810843 @default.
• W2325851421 cites W1993013485 @default.
• W2325851421 cites W1993461592 @default.
• W2325851421 cites W1994294469 @default.
• W2325851421 cites W1994325879 @default.
• W2325851421 cites W1997771374 @default.
• W2325851421 cites W2003090100 @default.
• W2325851421 cites W2004886491 @default.
• W2325851421 cites W2006152793 @default.
• W2325851421 cites W2007068681 @default.
• W2325851421 cites W2013835841 @default.
• W2325851421 cites W2023271753 @default.
• W2325851421 cites W2028462475 @default.
• W2325851421 cites W2030082962 @default.
• W2325851421 cites W2030582950 @default.
• W2325851421 cites W2030841140 @default.
• W2325851421 cites W2030976617 @default.
• W2325851421 cites W2031489293 @default.
• W2325851421 cites W2033925113 @default.
• W2325851421 cites W2048046732 @default.
• W2325851421 cites W2049063126 @default.
• W2325851421 cites W2052452404 @default.
• W2325851421 cites W2056285826 @default.
• W2325851421 cites W2060786880 @default.
• W2325851421 cites W2071881127 @default.
• W2325851421 cites W2075828898 @default.
• W2325851421 cites W2079473982 @default.
• W2325851421 cites W2081724410 @default.
• W2325851421 cites W2082070096 @default.
• W2325851421 cites W2086596892 @default.
• W2325851421 cites W2090521008 @default.
• W2325851421 cites W2095151766 @default.
• W2325851421 cites W2102336224 @default.
• W2325851421 cites W2102964261 @default.
• W2325851421 cites W2106824077 @default.
• W2325851421 cites W2111421101 @default.
• W2325851421 cites W2117991154 @default.
• W2325851421 cites W2143981217 @default.
• W2325851421 cites W2147390570 @default.
• W2325851421 cites W2165122270 @default.
• W2325851421 cites W2171656282 @default.
• W2325851421 cites W2172261176 @default.
• W2325851421 cites W2230728100 @default.
• W2325851421 cites W2527271326 @default.
• W2325851421 cites W3004465863 @default.
• W2325851421 cites W322044963 @default.
• W2325851421 cites W384984372 @default.
• W2325851421 cites W4242582203 @default.
• W2325851421 doi "https://doi.org/10.1021/ic101619y" @default.
• W2325851421 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21067213" @default.
• W2325851421 hasPublicationYear "2010" @default.
• W2325851421 type Work @default.
• W2325851421 sameAs 2325851421 @default.
• W2325851421 citedByCount "33" @default.
• W2325851421 countsByYear W23258514212012 @default.
• W2325851421 countsByYear W23258514212013 @default.
• W2325851421 countsByYear W23258514212014 @default.
• W2325851421 countsByYear W23258514212015 @default.
• W2325851421 countsByYear W23258514212016 @default.
• W2325851421 countsByYear W23258514212017 @default.
• W2325851421 countsByYear W23258514212018 @default.
• W2325851421 countsByYear W23258514212019 @default.
• W2325851421 countsByYear W23258514212020 @default.
• W2325851421 countsByYear W23258514212022 @default.
• W2325851421 crossrefType "journal-article" @default.
• W2325851421 hasAuthorship W2325851421A5005815538 @default.
• W2325851421 hasAuthorship W2325851421A5034849353 @default.
• W2325851421 hasAuthorship W2325851421A5059107732 @default.
• W2325851421 hasAuthorship W2325851421A5069680336 @default.
• W2325851421 hasAuthorship W2325851421A5077289752 @default.
• W2325851421 hasConcept C111592845 @default.
• W2325851421 hasConcept C115624301 @default.
• W2325851421 hasConcept C121332964 @default.
• W2325851421 hasConcept C145148216 @default.
• W2325851421 hasConcept C147597530 @default.
• W2325851421 hasConcept C152365726 @default.
• W2325851421 hasConcept C178790620 @default.
• W2325851421 hasConcept C180577832 @default.
• W2325851421 hasConcept C181500209 @default.
• W2325851421 hasConcept C184779094 @default.

• next