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- W2325893614 abstract "Synthesis of large-scale highly crystalline two-dimensional alloys is significant for revealing properties. Here, we have investigated the vapor growth process of high-quality bilayer CoxMo1–xS2 (x = 0.16) hexagonal nanosheets systematically. As the initial loading of the sulfur increases, the morphology of the CoxMo1–xS2 (0 < x ≤ 1) nanosheets becomes hexagons from David stars step by step at 680 °C. We find that Co atoms mainly distribute at the edge of nanosheets. When the temperature increases from 680 to 750 °C, high-quality cubic pyrite-type crystal structure CoS2 grows on the surface of CoxMo1–xS2 nanosheet gradually and forms hexagonal film induced by the nanosheet. Electrical transport measurements reveal that the CoxMo1–xS2 nanosheets and CoS2 films exhibit n-type semiconducting transport behavior and half-metallic behavior, respectively. Theoretical calculations of their band structures agree well with the experimental results." @default.
- W2325893614 created "2016-06-24" @default.
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- W2325893614 date "2015-01-15" @default.
- W2325893614 modified "2023-09-24" @default.
- W2325893614 title "Synthesis and Transport Properties of Large-Scale Alloy Co<sub>0.16</sub>Mo<sub>0.84</sub>S<sub>2</sub> Bilayer Nanosheets" @default.
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- W2325893614 doi "https://doi.org/10.1021/nn505048y" @default.
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