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• W2325991572 endingPage "9895" @default.
• W2325991572 startingPage "9888" @default.
• W2325991572 abstract "The oxidation and reduction of a redox-active aryl-substituted bis(imino)pyridine iron dicarbonyl has been explored to determine whether electron-transfer events are ligand- or metal-based or a combination of both. A series of bis(imino)pyridine iron dicarbonyl compounds, [((iPr)PDI)Fe(CO)(2)](-), ((iPr)PDI)Fe(CO)(2), and [((iPr)PDI)Fe(CO)(2)](+) [(iPr)PDI = 2,6-(2,6-(i)Pr(2)C(6)H(3)N═CMe)(2)C(5)H(3)N], which differ by three oxidation states, were prepared and the electronic structures evaluated using a combination of spectroscopic techniques and, in two cases, [((iPr)PDI)Fe(CO)(2)](+) and [((iPr)PDI)Fe(CO)(2)], metrical parameters from X-ray diffraction. The data establish that the cationic iron dicarbonyl complex is best described as a low-spin iron(I) compound (S(Fe) = ½) with a neutral bis(imino)pyridine chelate. The anionic iron dicarbonyl, [((iPr)PDI)Fe(CO)(2)](-), is also best described as an iron(I) compound but with a two-electron-reduced bis(imino)pyridine. The covalency of the neutral compound, ((iPr)PDI)Fe(CO)(2), suggests that both the oxidative and reductive events are not ligand- or metal-localized but a result of the cooperativity of both entities." @default.
• W2325991572 created "2016-06-24" @default.
• W2325991572 creator A5006849596 @default.
• W2325991572 creator A5068583934 @default.
• W2325991572 creator A5069380549 @default.
• W2325991572 creator A5087910041 @default.
• W2325991572 date "2011-06-13" @default.
• W2325991572 modified "2023-10-10" @default.
• W2325991572 title "Oxidation and Reduction of Bis(imino)pyridine Iron Dicarbonyl Complexes" @default.
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• W2325991572 doi "https://doi.org/10.1021/ic200730k" @default.
• W2325991572 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21667935" @default.
• W2325991572 hasPublicationYear "2011" @default.
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