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- W2326098824 abstract "Detection of mefenamic acid (M, non-steroidal anti-inflammatory drug, NSAIDs) and its metallodrug was investigated using electrospray ionization mass spectrometry (ESI-MS) and fluorescence spectroscopy. ESI-MS data (500 μL, 1×10-3 M) revealed high detection sensitivity for the drug and metallodrug. ESI-MS spectra revealed peaks at 242, 580, and 777 Da corresponding to [M+H]+, [63Cu(M-H)2(H2O)2+H]+, and [56Fe(M-H)3+H]+, respectively. The metal:mefenamic ratios of ESIMS spectra are in complete agreement with the fluorescence spectroscopy results (1:2 for Cu(II) and 1:3 for Fe(III)). ESI is a soft ionization technique that can be used on labile metallo-mefenamic acids and is promising for the detection of these species in environmental samples and biological fluids." @default.
- W2326098824 created "2016-06-24" @default.
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- W2326098824 date "2015-06-30" @default.
- W2326098824 modified "2023-09-28" @default.
- W2326098824 title "Soft Ionization of Metallo-Mefenamic Using Electrospray Ionization Mass Spectrometry" @default.
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- W2326098824 doi "https://doi.org/10.5478/msl.2015.6.2.43" @default.
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