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- W2326174912 abstract "The heat capacity of ${mathrm{Na}}_{1.5}{mathrm{Co}}_{2}{mathrm{O}}_{4}$ was measured from 10 to 330 K using a high-precision adiabatic calorimeter, and heat capacity anomalies were found around room temperature. The anomalies show three peaks at 288.7, 296.3, and 302.1 K, and the total enthalpy and entropy values are $675.7 {mathrm{J}mathrm{}mathrm{mol}}^{ensuremath{-}1}$ and $2.24 {mathrm{J}mathrm{}mathrm{K}}^{ensuremath{-}1} {mathrm{mol}}^{ensuremath{-}1},$ respectively. As the high-temperature phase could be undercooled below the peak temperatures, the three peaks should be related to the first-order phase transitions. However, magnetic susceptibility showed no anomaly at corresponding temperatures. On the other hand, an unknown diffraction peak was found in the x-ray diffraction measurement at 123 K, which indicated a new phase." @default.
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- W2326174912 date "2002-01-10" @default.
- W2326174912 modified "2023-09-25" @default.
- W2326174912 title "First-order phase transition inNa1.5Co2O4" @default.
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- W2326174912 doi "https://doi.org/10.1103/physrevb.65.052105" @default.
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