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- W2326281063 abstract "Noncatalytic hydrothermolyses of malto- and cello-oligosaccharides (di-, tri-, tetraose), linked by α- and β-1,4-glycosidic bonds, respectively, were investigated at 100–140 °C. In situ 13C NMR spectroscopy was applied to elucidate the position and pathways of the glycosidic bond breakage and the dependence of the hydrolysis rate on the bond type. Spectral analysis was carried out quantitatively as a function of time with the mass balance confirmed, and it was shown for both the malto- and the cello-oligosaccharides that the terminal d-glucose unit with a free anomeric carbon is selectively eliminated after transformation to d-fructose. Site-selective breakage of the glycosidic bonds proceeded on the order of hours. The initial apparent rates for terminal hydrolysis were found to be independent of the degree of oligomerization but dependent on the type of glycosidic bond. Rate constants were larger for the α-1,4-linked malto-oligosaccharides by a factor of 3–4 than for the β-1,4-linked cello-oligosaccharides. The pathways and mechanisms for the malto- and cello-oligosaccharide hydrothermolyses are common and can be understood in terms of the elementary reactions of the di- and monosaccharides." @default.
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- W2326281063 date "2012-10-05" @default.
- W2326281063 modified "2023-09-25" @default.
- W2326281063 title "Noncatalytic Hydrothermal Elimination of the Terminal d-Glucose Unit from Malto- and Cello-Oligosaccharides through Transformation to d-Fructose" @default.
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- W2326281063 doi "https://doi.org/10.1021/jp3034165" @default.
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