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- W2326341707 abstract "We present calculations of resonant Raman scattering (RRS) at the M4,5 thresholds of Gd in the scattering channel 3d104f7→3d94f8→[4p54f8↔4d84f9]. We have included in the final state the interaction between the two configurations within the brackets, having one 4p and two 4d holes, respectively. The influence of the configuration interaction on the scattering spectra is shown to be important. The calculations are made within a purely ionic model including only the spectral features dispersing with the incident photon energy and do not account for the M4 to M5 Coster-Kronig conversion. The calculations are compared with recent experimental results on Gd metal. The agreement is excellent when choosing the excitation energy in the M5 region. In the M4 region the calculations agree with the measurements by assuming that the Coster-Kronig contribution is approximated in shape by the RRS spectrum measured with direct M5 excitation. The implications of the results are discussed." @default.
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- W2326341707 date "2002-08-01" @default.
- W2326341707 modified "2023-09-27" @default.
- W2326341707 title "X-ray M4,5 resonant Raman scattering from Gd with final 4p hole: calculations with 4p–4d–4f configuration interaction in the final state and comparison with the experiment" @default.
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- W2326341707 doi "https://doi.org/10.1016/s0368-2048(02)00106-8" @default.
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