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- W2326341713 abstract "A highly oriented zeolitic imidazolate framework 8 (ZIF-8) composite membrane was prepared by seeding and secondary growth. By dip-coating, preformed ZIF-8 nanocrystals were attached to the surface of a porous α-alumina support using polyethyleneimine as the coupling agent. After solvothermal treatment, a continuous and well-intergrown ZIF-8 layer was obtained. X-ray diffraction analysis of the membrane showed preferred orientation of the {100} plane parallel to the support. Further time-dependent investigations by scanning and transmission electron microscopy as well as X-ray diffraction indicated that the preferred orientation develops during an evolutionary growth process. In gas mixture permeation experiments, the membrane showed good performance in H2/hydrocarbon separation. A sharp molecular sieve separation is observed for an equimolar H2/C3H8 mixture with a separation factor above 300." @default.
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- W2326341713 date "2011-03-22" @default.
- W2326341713 modified "2023-10-02" @default.
- W2326341713 title "Oriented Zeolitic Imidazolate Framework-8 Membrane with Sharp H<sub>2</sub>/C<sub>3</sub>H<sub>8</sub> Molecular Sieve Separation" @default.
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- W2326341713 doi "https://doi.org/10.1021/cm200555s" @default.
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