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• W2326364590 endingPage "5785" @default.
• W2326364590 startingPage "5782" @default.
• W2326364590 abstract "A one-pot synthesis of allenes by the 2-nitrobenzenesulfonylhydrazide-mediated coupling of hydroxyaldehydes or ketones with alkynyl trifluoroborate salts is reported. This mild process involves in situ formation of a sulfonylhydrazone that reacts with alkynyl trifluoroborates to generate a transient propargylic hydrazide species. Decomposition of this unstable hydrazide via an intermediate monoalkyldiazine produces the allene products through an alkene walk mechanism." @default.
• W2326364590 created "2016-06-24" @default.
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• W2326364590 date "2012-03-27" @default.
• W2326364590 modified "2023-10-14" @default.
• W2326364590 title "A Direct Synthesis of Allenes by a Traceless Petasis Reaction" @default.
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• W2326364590 doi "https://doi.org/10.1021/ja301489n" @default.
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