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- W2326402679 abstract "The torsional angles in 30 N-substituted benzamides and related compounds have been estimated by the use of the 13C substituent chemical shifts of the meta and para carbon atoms. Steric interaction between the N-substituted groups and the ortho hydrogen atoms of the benzene ring is the major determinant of non-planarity in these systems. A linear relationship between steric substituent constants of the N-substituted groups of some benzamides and the torsional angles is proposed. Dynamic processes involving rotation about the C-N bond, nitrogen inversion and ring inversion contribute a dynamic steric effect to the overall steric interaction. The preferred conformations of some N-substituted groups is also discussed." @default.
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- W2326402679 date "1981-01-01" @default.
- W2326402679 modified "2023-09-23" @default.
- W2326402679 title "Torsional angles in N-substituted benzamides and related compounds by carbon-13 N.M.R. chemical shifts" @default.
- W2326402679 doi "https://doi.org/10.1071/ch9810957" @default.
- W2326402679 hasPublicationYear "1981" @default.
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