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- W2326448090 abstract "The extraction of Uranium (VI) from aqueous media of varying pH values (0.3 �9.0) was studied using chloroform solution of 0.05M N,N`-ethylenebis(4-propionyl-2,4-dihydro-5methyl-2-phenyl-3H-pyrazol-3-oneimine) (H 2 PrEtP) Schiff base. The effect of 4 -propionyl2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-one (HPrP) as a mixed ligand in these extractions was also studied. The ligand H 2 PrEtP was shown to behave in solution as a very weak acidwith potentiometrically determined acid dissociation constants pK a of 6.1±0.1 and 7.6±0.1.Colorimetricmethod was used to determine the Uranium(VI) concentrations in aqueous media after extraction processes. Slope analysis showed that the extracteduranyl complexes were UO 2 (HPrEtP).X in the absence of the mixed ligand (H 2 PrEtP/HPrP) and UO 2 (HPrEtP)HPrP.X in the presence of HPrP as a mixed ligand, with the excess anion X - coming from the buffers. The pH" @default.
- W2326448090 created "2016-06-24" @default.
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- W2326448090 date "2013-01-10" @default.
- W2326448090 modified "2023-10-09" @default.
- W2326448090 title "Solvent Extraction Studies of Uranium (VI) from Aqueous Media into Chloroform Solution of N,N´-ethylenebis(4-propionyl-2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-oneimine)" @default.
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- W2326448090 doi "https://doi.org/10.9734/acsj/2013/4155" @default.
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