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- W2326467931 abstract "Codehydrocoupling (in the presence of various inorganic B, Al-hydrides) followed by borane-capping (with Ph2BCl) of 1,1-dihydrotetraphenylsilole (1) and 1,1-dihydrotetraphenylgermole (2) (9:1 mole ratio) gave electroluminescent poly(silole-co-germole)s containing borane-ends (3) in high yield. The polymerization yield and molecular weight with Selectrides increase in the order L-Selectride < N-Selectride < K-Selectride. The molecular weights with B, Al-inorganic hydrides increase in the order L-Selectride < Red-Al <N-Selectride < K-Selectride < Super-Hydride. The borane-terminated copolymer 3 emits at 522 nm and are electroluminescent at 521 nm. The fluorescence quantum yield of 3 in toluene is (1.60 +/- 0.30) x 10(-2). The emission color is green and the maximum brightness of the device is 2,753 cd/m2 with a luminous efficiency of 0.66 Im/W. The borane end group exhibited no appreciable effect on the luminescent properties of 3. The electroluminescent copolymer 3 with boranyl end group is hence a good candidate for PLED fabrication." @default.
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- W2326467931 date "2012-05-01" @default.
- W2326467931 modified "2023-10-18" @default.
- W2326467931 title "Synthesis and Characterization of Borane-Terminated Poly(silole-<I>co</I>-germole) for the Evaluation of Luminescent PLED" @default.
- W2326467931 doi "https://doi.org/10.1166/jnn.2012.5927" @default.
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