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- W2326476005 abstract "A rapid synthetic route to nanocrystalline carbon-incorporated mixed metal oxide nanocomposites with enhanced electrode performance for lithium ion batteries is developed by applying a very short heat-treatment of layered double hydroxide (LDH) precursor under C2H2 flow. Employing C2H2 atmosphere makes possible the rapid synthesis of nanocrystalline C–NiO–NiFe2O4 nanocomposite via the calcination of the Ni–Fe–LDH precursor at 300 °C in a very short period of 5 min. In the case of ambient atmosphere, a prolonged calcination time of several hours is demanded to induce a complete phase transformation from Ni–Fe–LDH to electrochemically active NiO–NiFe2O4 nanocomposite, highlighting the usefulness of C2H2 atmosphere in promoting the formation of mixed metal oxide nanocomposite. The present C–NiO–NiFe2O4 nanocomposite shows much better anode performance for lithium ion batteries with greater discharge capacity and better cyclability than do the NiO–NiFe2O4 nanocomposites prepared by the prolonged calcination of LDH under ambient atmosphere. The superior electrode activity of the present C–NiO–NiFe2O4 nanocomposite is attributable to the optimization of charge transfer induced by the enhanced electrical conductivity and a short diffusion length of Li ion. The present C2H2-assisted phase transition of LDH precursor provides a convenient, economic, and scalable synthetic way to carbon–mixed metal oxide nanocomposites with promising electrode performance for lithium ion batteries." @default.
- W2326476005 created "2016-06-24" @default.
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- W2326476005 date "2016-04-18" @default.
- W2326476005 modified "2023-09-27" @default.
- W2326476005 title "Rapid Synthetic Route to Nanocrystalline Carbon-Mixed Metal Oxide Nanocomposites with Enhanced Electrode Functionality" @default.
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- W2326476005 doi "https://doi.org/10.1021/acs.jpcc.6b00841" @default.
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