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• W2326485841 startingPage "1094" @default.
• W2326485841 abstract "The introduction of acid-degradable acetal moieties into a hyperbranched polyether backbone has been achieved by the design of a novel epoxide-based degradable inimer. This new monomer, namely, 1-(glycidyloxy)ethyl ethylene glycol ether (GEGE), has been copolymerized in the anionic ring-opening polymerization (AROP) with ethylene oxide (EO) or glycidol (G), respectively, yielding branched polyethers, that is, P(EO-co-GEGE) and P(G-co-GEGE), that possess an adjustable amount of acid-cleavable acetal units. In addition, a novel class of multiarm star copolymers P(G-co-GEGE-g-EO) with acid-labile polyether core and PEG side chains was synthesized by using the P(G-co-GEGE) copolymers as multifunctional macroinitiators for AROP of EO. The new materials have been characterized in a detailed manner, revealing narrow to moderate molecular weight distributions. The degradation of these polymers under acidic conditions was characterized via SEC and 1H NMR spectroscopy." @default.
• W2326485841 created "2016-06-24" @default.
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• W2326485841 date "2012-08-15" @default.
• W2326485841 modified "2023-10-14" @default.
• W2326485841 title "Branched Acid-Degradable, Biocompatible Polyether Copolymers via Anionic Ring-Opening Polymerization Using an Epoxide Inimer" @default.
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• W2326485841 doi "https://doi.org/10.1021/mz300265z" @default.
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