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• W2326519982 abstract "Ten substituted benzoate complexes of Pr3+ of the type [Pr(XC6H4COO)3(H2O)n(DMF)m]p·(DMF)q (X = OCH3, NO2, OH, F, Cl, NH2) have been synthesized, and for eight of these crystallographic data are available. The electronic absorption and emission spectra of the complexes have been recorded and interpreted at temperatures down to 10 K for transitions involving the 3P0 and 1D2 J-multiplet terms. Generally, the electron-withdrawing groups X in the benzoate moiety lead to higher 3P0 energy than electron-donating groups. Empirical relations have been found between the energies of the 3P0 and 1D2(1) levels and the Hammett sigma constants for substituents and the unit cell volume per Pr3+ ion. The latter relationship is indicative of a correlation between the electronic state energy and the ligand dipole polarizability. This has been confirmed by reference to literature data for the LaX3:Pr3+ systems, so that the ligand dipole polarizability is a key factor in determining the nephelauxetic shifts of 4fN ions in crystals." @default.
• W2326519982 created "2016-06-24" @default.
• W2326519982 creator A5032010185 @default.
• W2326519982 creator A5084853487 @default.
• W2326519982 date "2014-12-17" @default.
• W2326519982 modified "2023-10-01" @default.
• W2326519982 title "Relation between Ligand Design and Transition Energy for the Praseodymium Ion in Crystals" @default.
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• W2326519982 doi "https://doi.org/10.1021/jp511524w" @default.
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