FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2326544977> ?p ?o ?g. }

• W2326544977 endingPage "1294" @default.
• W2326544977 startingPage "1279" @default.
• W2326544977 abstract "Mr. Brightside: Imidazo[1,2-a]pyridine derivatives show blue, green, or yellow fluorescence depending on the nature of the substituents. Quadrupolar dyes that feature this scaffold as an electron donor display an advantageous combination of optical properties, including two-photon brightness (40 GM). A library of imidazo[1,2-a]pyridines was synthesized by using the Gevorgyan method and their linear and non-linear optical properties were studied. Derivatives that contained both electron-donating and electron-withdrawing groups at the 2 position were comprehensively investigated. Their emission quantum yield ranged between 0.2–0.7 and it was shown to depend on the substitution pattern, most notably that on the phenyl ring. Electron-donating substituents improved the luminescence performance of these compounds, whereas electron-withdrawing substituents led to a more erratic behavior. Substitution on the six-membered ring had less effect on the fluorescence properties. Extension of the delocalization increased the luminescence quantum yield. A new quadrupolar system was designed that contained two imidazo[1,2-a]pyridine units on its periphery and a 1,4-dicyanobenzene unit at its center. This system exhibited a large Stokes-shifted luminescence that was affected by the polarity and rigidity of the solvent, which was ascribed to emission from an excited state with strong charge-transfer character. This quadrupolar feature also led to an acceptable two-photon absorption response in the NIR region. Biblioteka 2,3-dipodstawionych pochodnych imidazo[1,2-a]pirydyny została zsynteyzowana. Zbadano ich właściowsci optyczne i określono relacje pomiędzy strukturą a tymi właściwościami. Otrzymano dwie złożone pochodne imidazo[1,2-a]pirydyny o układzie D–A–D. Związki te wykazywały dosyć wysoki przekrój czynny na absoprcję dwufotonową oraz dużą wydajność kwantową fluorescencji. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
• W2326544977 created "2016-06-24" @default.
• W2326544977 creator A5000244729 @default.
• W2326544977 creator A5025294916 @default.
• W2326544977 creator A5059920358 @default.
• W2326544977 creator A5063867141 @default.
• W2326544977 creator A5064777614 @default.
• W2326544977 creator A5064868028 @default.
• W2326544977 date "2013-04-05" @default.
• W2326544977 modified "2023-10-17" @default.
• W2326544977 title "Bright, Fluorescent Dyes Based on Imidazo[1,2-<i>a</i>]pyridines that are Capable of Two-Photon Absorption" @default.
• W2326544977 cites W1968730224 @default.
• W2326544977 cites W1972057374 @default.
• W2326544977 cites W1981546475 @default.
• W2326544977 cites W1991262047 @default.
• W2326544977 cites W1992644329 @default.
• W2326544977 cites W1993033978 @default.
• W2326544977 cites W1994026975 @default.
• W2326544977 cites W1996328818 @default.
• W2326544977 cites W1998492630 @default.
• W2326544977 cites W1998698117 @default.
• W2326544977 cites W1999829809 @default.
• W2326544977 cites W2000461547 @default.
• W2326544977 cites W2005510158 @default.
• W2326544977 cites W2008340191 @default.
• W2326544977 cites W2019157182 @default.
• W2326544977 cites W2019649880 @default.
• W2326544977 cites W2020586725 @default.
• W2326544977 cites W2022743157 @default.
• W2326544977 cites W2036457921 @default.
• W2326544977 cites W2038205928 @default.
• W2326544977 cites W2040632908 @default.
• W2326544977 cites W2048510596 @default.
• W2326544977 cites W2049346936 @default.
• W2326544977 cites W2053338082 @default.
• W2326544977 cites W2053563133 @default.
• W2326544977 cites W2072985495 @default.
• W2326544977 cites W2073219485 @default.
• W2326544977 cites W2079503940 @default.
• W2326544977 cites W2079613047 @default.
• W2326544977 cites W2079689682 @default.
• W2326544977 cites W2082770145 @default.
• W2326544977 cites W2084551704 @default.
• W2326544977 cites W2086265337 @default.
• W2326544977 cites W2086497464 @default.
• W2326544977 cites W2094123053 @default.
• W2326544977 cites W2104703767 @default.
• W2326544977 cites W2105184358 @default.
• W2326544977 cites W2107605751 @default.
• W2326544977 cites W2113504999 @default.
• W2326544977 cites W2121993611 @default.
• W2326544977 cites W2122585739 @default.
• W2326544977 cites W2126806532 @default.
• W2326544977 cites W2141821787 @default.
• W2326544977 cites W2147827788 @default.
• W2326544977 cites W2149222572 @default.
• W2326544977 cites W2155085748 @default.
• W2326544977 cites W2159122993 @default.
• W2326544977 cites W2161656854 @default.
• W2326544977 cites W2172442948 @default.
• W2326544977 cites W2175850637 @default.
• W2326544977 cites W2176242436 @default.
• W2326544977 cites W2312405913 @default.
• W2326544977 cites W2316435970 @default.
• W2326544977 cites W2320479495 @default.
• W2326544977 cites W2329049066 @default.
• W2326544977 cites W2331828406 @default.
• W2326544977 cites W2332245777 @default.
• W2326544977 cites W2333004715 @default.
• W2326544977 cites W2949535234 @default.
• W2326544977 cites W2949591720 @default.
• W2326544977 cites W2949592929 @default.
• W2326544977 cites W2950969446 @default.
• W2326544977 cites W2951415419 @default.
• W2326544977 cites W2952673290 @default.
• W2326544977 cites W4229884109 @default.
• W2326544977 cites W4230739685 @default.
• W2326544977 cites W4241512851 @default.
• W2326544977 doi "https://doi.org/10.1002/asia.201300058" @default.
• W2326544977 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23564658" @default.
• W2326544977 hasPublicationYear "2013" @default.
• W2326544977 type Work @default.
• W2326544977 sameAs 2326544977 @default.
• W2326544977 citedByCount "51" @default.
• W2326544977 countsByYear W23265449772013 @default.
• W2326544977 countsByYear W23265449772014 @default.
• W2326544977 countsByYear W23265449772015 @default.
• W2326544977 countsByYear W23265449772016 @default.
• W2326544977 countsByYear W23265449772017 @default.
• W2326544977 countsByYear W23265449772018 @default.
• W2326544977 countsByYear W23265449772019 @default.
• W2326544977 countsByYear W23265449772020 @default.
• W2326544977 countsByYear W23265449772022 @default.
• W2326544977 countsByYear W23265449772023 @default.
• W2326544977 crossrefType "journal-article" @default.
• W2326544977 hasAuthorship W2326544977A5000244729 @default.
• W2326544977 hasAuthorship W2326544977A5025294916 @default.
• W2326544977 hasAuthorship W2326544977A5059920358 @default.

• next