FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2326558963> ?p ?o ?g. }

• W2326558963 endingPage "6994" @default.
• W2326558963 startingPage "6987" @default.
• W2326558963 abstract "A new water-soluble Pybox ligand, 1, has been synthesized and found to crystallize in the monoclinic P2(1)/n space group with unit cell parameters a = 6.0936(1) Å, b = 20.5265(4) Å, c = 12.0548(2) Å, and β = 90.614(1)°. In the crystal, a water molecule is bound through hydrogen-bonding interactions to the nitrogen atoms of the oxazoline rings. This ligand was used to complex a variety of lanthanide ions, opening up new avenues for luminescence and catalysis in aqueous environment. These complexes are highly luminescent in aqueous solutions, in acetonitrile, and in the solid state. Aqueous quantum yields are high at 30.4% for Eu(III), 26.4% for Tb(III), 0.32% for Yb(III), and 0.11% for Nd(III). Er(III) did not luminesce in water, but an emission efficiency of 0.20% could be measured in D(2)O. Aqueous emission lifetimes were also determined for the visible emitting lanthanide ions and are 1.61 ms for Eu(III) and 1.78 ms for Tb(III). Comparing emission lifetimes in deuterated and nondeuterated water indicates that no water molecules are coordinated to the metal ion. Speciation studies show that three species form successively in solution and the log β values are 5.3, 9.6, and 13.8 for Eu(III) and 5.3, 9.2, and 12.7 for Tb(III) for 1:1, 2:1, and 3:1 ligand to metal ratios, respectively." @default.
• W2326558963 created "2016-06-24" @default.
• W2326558963 creator A5033900071 @default.
• W2326558963 creator A5049183431 @default.
• W2326558963 creator A5064127239 @default.
• W2326558963 date "2012-04-13" @default.
• W2326558963 modified "2023-10-18" @default.
• W2326558963 title "A Water-Soluble Pybox Derivative and Its Highly Luminescent Lanthanide Ion Complexes" @default.
• W2326558963 cites W1964935433 @default.
• W2326558963 cites W1967782701 @default.
• W2326558963 cites W1968830850 @default.
• W2326558963 cites W1970803380 @default.
• W2326558963 cites W1971370642 @default.
• W2326558963 cites W1974367442 @default.
• W2326558963 cites W1975355765 @default.
• W2326558963 cites W1977868435 @default.
• W2326558963 cites W1978893429 @default.
• W2326558963 cites W1981990500 @default.
• W2326558963 cites W1983523303 @default.
• W2326558963 cites W1984510177 @default.
• W2326558963 cites W1984845779 @default.
• W2326558963 cites W1985062662 @default.
• W2326558963 cites W1986625209 @default.
• W2326558963 cites W1987902052 @default.
• W2326558963 cites W1991744744 @default.
• W2326558963 cites W1994830388 @default.
• W2326558963 cites W1995547744 @default.
• W2326558963 cites W1998714557 @default.
• W2326558963 cites W1999672402 @default.
• W2326558963 cites W2004207281 @default.
• W2326558963 cites W2007315895 @default.
• W2326558963 cites W2008979776 @default.
• W2326558963 cites W2009665696 @default.
• W2326558963 cites W2009969756 @default.
• W2326558963 cites W2011847358 @default.
• W2326558963 cites W2013679067 @default.
• W2326558963 cites W2018127838 @default.
• W2326558963 cites W2020784900 @default.
• W2326558963 cites W2021895104 @default.
• W2326558963 cites W2023093063 @default.
• W2326558963 cites W2023506225 @default.
• W2326558963 cites W2027851019 @default.
• W2326558963 cites W2030376196 @default.
• W2326558963 cites W2032704980 @default.
• W2326558963 cites W2034341270 @default.
• W2326558963 cites W2038120826 @default.
• W2326558963 cites W2038567620 @default.
• W2326558963 cites W2047282120 @default.
• W2326558963 cites W2047574377 @default.
• W2326558963 cites W2049388865 @default.
• W2326558963 cites W2052479523 @default.
• W2326558963 cites W2053874223 @default.
• W2326558963 cites W2054643040 @default.
• W2326558963 cites W2056407264 @default.
• W2326558963 cites W2056781919 @default.
• W2326558963 cites W2060291238 @default.
• W2326558963 cites W2061040716 @default.
• W2326558963 cites W2067214444 @default.
• W2326558963 cites W2067995809 @default.
• W2326558963 cites W2070907932 @default.
• W2326558963 cites W2074060825 @default.
• W2326558963 cites W2075642649 @default.
• W2326558963 cites W2076355134 @default.
• W2326558963 cites W2077781402 @default.
• W2326558963 cites W2080600376 @default.
• W2326558963 cites W2086452514 @default.
• W2326558963 cites W2087762156 @default.
• W2326558963 cites W2091226372 @default.
• W2326558963 cites W2094347957 @default.
• W2326558963 cites W2095571315 @default.
• W2326558963 cites W2098150681 @default.
• W2326558963 cites W2100042879 @default.
• W2326558963 cites W2102838682 @default.
• W2326558963 cites W2110081426 @default.
• W2326558963 cites W2110875830 @default.
• W2326558963 cites W2112737064 @default.
• W2326558963 cites W2114651945 @default.
• W2326558963 cites W2116835469 @default.
• W2326558963 cites W2122547130 @default.
• W2326558963 cites W2123416667 @default.
• W2326558963 cites W2126578481 @default.
• W2326558963 cites W2134356241 @default.
• W2326558963 cites W2138520198 @default.
• W2326558963 cites W2149115397 @default.
• W2326558963 cites W2151859760 @default.
• W2326558963 cites W2155465461 @default.
• W2326558963 cites W2155645504 @default.
• W2326558963 cites W2160047705 @default.
• W2326558963 cites W2164087897 @default.
• W2326558963 cites W2171219272 @default.
• W2326558963 cites W2171357337 @default.
• W2326558963 cites W2171725030 @default.
• W2326558963 cites W2324330217 @default.
• W2326558963 cites W2329654212 @default.
• W2326558963 cites W2950386958 @default.
• W2326558963 cites W2952219656 @default.
• W2326558963 cites W4250282847 @default.
• W2326558963 cites W804076139 @default.

• next