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- W2326616732 abstract "A highly diastereoselective methodology for the preparation of various substituted piperidines via Negishi cross-couplings with (hetero)aryl iodides was developed. Depending on the position of the C−Zn bond relative to the nitrogen (position 2 vs position 4), the stereoselectivity of the coupling can be directed toward either the trans- or cis-2,4-disubstituted products. Density functional theory calculations on the relative stabilities of the Zn and Pd intermediates were performed to explain the high diastereoselectivities obtained. A novel 1,2-migration of Pd further expands this method to the stereoselective preparation of 5-aryl-2,5-disubstituted piperidines." @default.
- W2326616732 created "2016-06-24" @default.
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- W2326616732 date "2011-03-09" @default.
- W2326616732 modified "2023-10-15" @default.
- W2326616732 title "Highly Diastereoselective Arylations of Substituted Piperidines" @default.
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- W2326616732 doi "https://doi.org/10.1021/ja201008e" @default.
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