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- W2326641004 abstract "Abstract The concentration stability constants for CuS04 in various mixed solvents, viz ethanol-water, isopropa-nol-water and dioxane-water, having a composition of organic solvent of 0, 5, 10, 15,20 and 25 mass per cent were measured spectrophotometrically at 298 ±0.5 K using NaC104 as supporting electrolyte. The total ionic strength range of the solutions are 0.06-4.0mol dm−3 and pH = 4–5. The thermodynamic stability constants CuS04 were obtained by a polynomial approximation based on Pitzer's theory. Finally, the standard free energies of transfer of the coordination reaction, ΔG°…, from pure water to mixed solvent were obtained and the electrostatic part of ΔG°… was calculated based on Beveridge's theory." @default.
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- W2326641004 date "1990-01-01" @default.
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- W2326641004 title "The Influence of Medium on the Stability of Coordination Compounds. III. The System CuSO4-NaClO4-Organic Solvents-H2O" @default.
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- W2326641004 doi "https://doi.org/10.1080/00958979009408182" @default.
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